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Facile Route Synthesis of Novel Graphene Oxide-β-cyclodextrin Nanocomposite and Its Application as Adsorbent for Removal of Toxic Bisphenol A from the Aqueous Phase

机译:新型氧化石墨烯-β-环糊精纳米复合材料的简便路线合成及其作为吸附剂从水相中去除有毒双酚A的应用

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摘要

In-situ synthesized novel nanocomposite graphene oxide–β-cyclodextrin (GO–CD) was applied as adsorbent for swift adsorption and elimination of hazardous endocrine disrupting compounds, such as bisphenol A (BPA), from the solvent phase of an aqueous solution. Endocrine disrupting compounds are highly toxic substances that cannot be removed from treated wastewater through conventional methods. The optimized values of effective parameters were 10 min (contact time), 25 mg (adsorbent dosage), 9 (pH) and 100 mgL−1 (initial concentration) these values were optimized using batch adsorption study. The equilibrium adsorption and kinetics data were well fitted and in good agreement with Langmuir adsorption isotherms and pseudo-second order kinetic adsorption model. The Qmax of GO–CD was approximately 373.4 mg·g− 1, which is significantly higher than that of existing adsorbents. Hence, the developed adsorbent could be efficiently used for rapid adsorption and removal of noxious impurities.
机译:原位合成的新型纳米复合氧化石墨烯-β-环糊精(GO-CD)被用作吸附剂,用于从水溶液的溶剂相中快速吸附和消除有害的内分泌干扰化合物,例如双酚A(BPA)。破坏内分泌的化合物是剧毒物质,无法通过常规方法从处理后的废水中去除。有效参数的最佳值是10分钟(接触时间),25 mg(吸附剂剂量),9(pH)和100 mgL-1(初始浓度),这些值使用批量吸附研究进行了优化。平衡吸附和动力学数据拟合得很好,并与Langmuir吸附等温线和拟二阶动力学吸附模型良好吻合。 GO–CD的Qmax约为373.4 mg·g-1,显着高于现有吸附剂的Qmax。因此,开发的吸附剂可以有效地用于快速吸附和去除有害杂质。

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