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Gasification of Empty Fruit Bunch with Carbon Dioxide In An Entrained Flow Gasifier for Syngas Production

机译:用气流床气化炉中的二氧化碳气化空果束以生产合成气

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摘要

The main objectives of this work are to study the gasification of EFB in an atmospheric entrained flow gasifier, using carbon dioxide (CO2) as its gasifying agent and to determine the optimum gasification operating conditions, which includes temperature and the oxidant to fuel (OTF) ratio. These were evaluated in terms of important gasification parameters such as the concentration of hydrogen (H2) and carbon monoxide (CO) produced the syngas ratio H2/CO and carbon conversion. The gasification reactions take place in the presence of CO2 at very high reaction rate because of the high operating temperature (700°C - 900°C). The use of CO2 as the oxidant for gasification process can improve the composition of syngas produced as in the Boudouard reaction. Rise of reaction temperature which is 900°C will increase the concentration of both H2 & CO by up to 81 and 30 respectively, though their production were decreased after the OTF ratio of 0.6 for temperature 700°C & 800°C and OTF ratio 0.8 for temperature 750°C. The operating temperature must be higher than 850°C to ensure the Boudouard reaction become the more prominent reaction for the biomass gasification. The syngas ratio obtained was in the range of ≈ 0.6 − 2.4 which is sufficient for liquid fuel synthesis. For the carbon conversion, the highest fuel conversion recorded at temperature 850°C for all OTF ratios. As the OTF ratio increases, it was found that there was an increase in the formation of CO and H2. This suggests that to achieve higher carbon conversion, high operating temperature and OTF ratio are preferable. This study provides information on the optimum operating conditions for the gasification of biomass, especially the EFB, hence may upsurge the utilization of biomass waste as an energy source.
机译:这项工作的主要目的是研究大气夹带流化气化炉中EFB的气化,使用二氧化碳(CO2)作为气化剂,并确定最佳的气化操作条件,包括温度和燃料氧化剂(OTF)比。根据重要的气化参数,例如氢气(H2)和一氧化碳(CO)的浓度,产生的合成气比H2 / CO和碳转化率,对这些参数进行了评估。由于高的操作温度(700℃至900℃),所以在CO 2存在下以非常高的反应速率进行气化反应。使用CO 2作为气化过程的氧化剂可以改善在Boudouard反应中产生的合成气的组成。反应温度升高900°C会使H2和CO的浓度分别增加81和30,尽管在温度700°C和800°C的OTF比为0.6且OTF比为0.8的情况下,它们的产生均降低了温度为750°C。操作温度必须高于850°C,以确保Boudouard反应成为生物质气化的更为突出的反应。所获得的合成气比率在≈0.6-2.4的范围内,足以用于液体燃料合成。对于碳转化,所有OTF比率在850°C的温度下记录的最高燃料转化率。随着OTF比率的增加,发现CO和H 2的形成增加。这表明为了实现更高的碳转化率,优选高工作温度和OTF比。这项研究提供了有关气化生物质(尤其是EFB)的最佳操作条件的信息,因此可能会提高生物质废物作为能源的利用率。

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