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Alternating substrate/ligand-metal coordination enables a low-energy pathway for C-O bond cleavage in the electrocatalytic reduction of carbon dioxide

机译：交替的基材/配体 - 金属配位使得能够在电催化还原二氧化碳中的C-O键切割的低能量通路

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Hemlata Agarwala; Xiaoyu Chen; Julien R. Lyonnet; Ben A Johnson; Mårten Ahlquist; Sascha Ott;
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1. Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C-O Bond in the Catalyzed Electrochemical Reduction of CO_2 [J] . Cyrille Costentin, Samuel Drouet, Guillaume Passard, Journal of the American Chemical Society . 2013,第24期

机译：在电催化过程中质子耦合的重原子键的电子转移裂解。催化电化学还原CO_2中C-O键的裂解
2. Carbon-Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C-O Bond Cleavage in Esters [J] . Trovitch RJ, Lobkovsky E, Bouwkamp MW, Organometallics . 2008,第23期

机译：双（亚氨基）吡啶铁化合物的碳-氧键裂解：催化剂失活途径和酯中酰基C-O键裂解的观察。
3. Reactions of a Ru(II) Phenyl Complex with Substrates that Possess C-N or C-O Multiple Bonds:C-C Bond Formation,N-H Bond Cleavage,and Decarbonylation Reactions [J] . John P.Lee, Karl A.Pittard, Nathan J.DeYonker, Organometallics . 2006,第6期

机译：Ru（II）苯基络合物与具有C-N或C-O多个键的底物的反应：C-C键形成，N-H键裂解和脱羰反应
4. In-situ FTIR spectroelectrochemical studies on the electrocatalytic reduction of carbon dioxide by a ruthenium carbonyl complex [C] . Kwok-Yin Wong, So-Ngan Pun Sino-France Workshop on Surface Electrochemistry of Molecules of Biological Interest and Biosensor Application . 2001

机译：原位FTIR光谱电化学研究关于钌羰基络合物电催化还原二氧化碳
5. I. Symmetrical ligand bridged bimetallic complexes of rhenium(I): Implications for electrocatalytic reduction of carbon dioxide. II. Unimolecular excited state relaxation pathways in polypyridyl complexes of rhenium(I). [D] . Baiano, John Augustus. 1992

机译：I. ligand的对称配体桥联双金属络合物（I）：对电催化还原二氧化碳的影响。二。 poly（I）聚吡啶配合物中的单分子激发态弛豫途径。
6. Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin [O] . Jing Shen, Ruud Kortlever, Recep Kas, -1

机译：固定化钴原卟啉将二氧化碳电催化还原为一氧化碳和甲烷
7. Alternating substrate/ligand-metal coordination enables a low-energy pathway for C-O bond cleavage in the electrocatalytic reduction of carbon dioxide [O] . Hemlata Agarwala, Xiaoyu Chen, Julien R. Lyonnet, 2021

机译：交替的基材/配体 - 金属配位使得能够在电催化还原二氧化碳中的C-O键切割的低能量通路
8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

Alternating substrate/ligand-metal coordination enables a low-energy pathway for C-O bond cleavage in the electrocatalytic reduction of carbon dioxide

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