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>Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate Ph_2BP^(tBu)_2Cu(η^1-N_2CR_2), Ph_2BP^(tBu)_2Cu(CPh_2), and Ph_2BP^(tBu)_2Cu–N(CPh_2)(NCPh_2)
【2h】
Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate Ph_2BP^(tBu)_2Cu(η^1-N_2CR_2), Ph_2BP^(tBu)_2Cu(CPh_2), and Ph_2BP^(tBu)_2Cu–N(CPh_2)(NCPh_2)
[Ph_2BP^(tBu)_2]Cu–L complexes react with diazoalkanes to generate structurally unusual η^1-diazoalkane adducts, a terminal carbene, and an η^1-azine adduct.
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