Measuring Composition Growth of Ion Clusters of Sulfuric Acid, Ammonia, Amines Oxidized Organics as First Steps of Nucleation in the CLOUD Experiment

摘要

The mechanisms behind the nucleation of vapors forming new particles in the atmosphere had been proven difficult to establish. One main aim of the CLOUD experiment was to explore in detail these first steps of atmospheric new particle formation by performing extremely well controlled laboratory experiments. We examined nucleation and growth in the presence of different mixtures of vapors, including sulfuric acid, ammonia, dimethylamine, and oxidation products of pinanediol or α-pinene. Among the employed state-of-the-art instrumentation, a high-resolution mass spectrometer that directly sampled negatively charged ions and clusters proved particularly useful. We were able to resolve most of the chemical compositions found for charged sub-2nm clusters and to observe their growth in time. These compositions reflected the mixture of condensable vapors in the chamber and the role of each individual vapor in forming sub-2nm clusters could be explored. By inter-comparing between individual experiments and ambient observations, we try to establish which vapors participate in nucleation in the actual atmosphere, and how.