Theory of Semiclassical Transition Probabilities (S Matrix) for Inelastic and Reactive Collisions. Uniformization with Elastic Collision Trajectories

摘要

A canonical transformation is described for uniformizing the coordinates used in Paper I of this series.udFor comparison with the results of Paper III, which based a uniformization on exact trajectories, theudpresent article describes one based on elastic collision trajectories. The question of invariance of S-matrixudelements with respect to semiclassical unitary transformations is also discussed.