Franck-Condon factors and observed band strength distribution in the vibrational structure of the Ag_2 D-X band system

摘要

Potential curves for the X_1Σ_g^+ and D_1Σ_u^+ states of three diatomic silver isotopomers, ^(107)Ag_2, ^(107)Ag^(109)Ag and ^(109)Ag_2, were determined from the best available molecular constants by the Rydberg-Klein-Rees method. From these potentials, Franck-Condon factors and band-origin wave numbers were computed, and the reliability of the obtained values was verified by comparison with the observed band strength distribution and the measured band origin positions in a previously recorded D-X spectrum. The ratios of the Franck-Condon factors to those of corresponding isotopic bands were found to be very close to unity, revealing only a very small isotopic effect on the Franck Condon factors of Ag_2 D-X bands. The isotopic shifts of the calculated band origins agree well with previously measured displacements of band heads.