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Enhanced sensitivity for the differential pulse polarographic determination of Mo(VI) based on adsorption catalytic current

机译:基于吸附催化电流提高了差分脉冲极谱法测定MO(VI)的敏感性

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摘要

the adsorption catalytic current in a medium containingudchlorate and 8-hydroxyquinoline (exine) is suggested for theuddetermination of molybdenum(VI). Experimental conditionsudsuch as pH and the composition of supporting electrolyte have been optimized to get a linear calibration graph at trace levels of Mo(VI). The sensitivity for molybdenum can be considerably enhanced by this method. The influence of possible interferences on the catalytic current has been investigated. The sensitivity of the method is compared with those obtained for other DPP methods for molybdenum. A detection limit of 1.0 1Q-8 mol/L has been found.
机译:建议在 udchlorate和8-hydroxyquinoline(exine)介质中的吸附催化电流用于对钼(VI)的测定。已优化了诸如pH和支持电解质的组成等实验条件,以获得痕量Mo(VI)的线性校准图。通过这种方法可以大大提高钼的敏感性。已经研究了可能的干扰对催化电流的影响。将该方法的灵敏度与其他DPP钼方法获得的灵敏度进行了比较。检出限为1.0 1Q-8 mol / L。

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