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Characterizations of cupric oxide thin films on glass and silicon substrates by radio frequency magnetron sputtering

机译:射频磁控溅射表征玻璃和硅衬底上的氧化铜薄膜

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摘要

Cupric oxide (CuO) thin films were prepared on a glass and silicon (Si) substrates by radio frequency magnetron sputtering system. The structural, optical and electrical properties of CuO films were characterized by X-ray diffraction (XRD), atomic force microscopy (AFM), Fourier transform infrared spectrometer, ultra-violet visible spectrophotometer, respectively, four point probe techniques and Keithley 4200 semiconductor characterization system. The XRD result showed that single phase CuO thin films with monoclinic structure were obtained. AFM showed well organized nano-pillar morphology with root mean square surface roughness for CuO thin films on glass and Si substrates were 3.64 and 1.91 nm, respectively. Infrared reflectance spectra shown a single reflection peak which is corresponding to CuO optical phonon mode and it confirmed that only existence of CuO composition on both substrates. The optical direct band gap energy of the CuO film grown on glass substrate, which is calculated from the optical transmission measurement was 1.37 eV. Finally, it was found that the deposited CuO films are resistive and the palladium formed ohmic contact for CuO on glass and schottky contact for CuO on Si.
机译:通过射频磁控溅射系统在玻璃和硅(Si)基板上制备了氧化铜(CuO)薄膜。通过X射线衍射(XRD),原子力显微镜(AFM),傅立叶变换红外光谱仪,紫外可见分光光度计,四点探针技术和Keithley 4200半导体表征来表征CuO膜的结构,光学和电学性质。系统。 XRD结果表明,获得了具有单斜晶结构的单相CuO薄膜。 AFM显示出组织良好的纳米柱形态,在玻璃和Si衬底上的CuO薄膜的均方根表面粗糙度分别为3.64和1.91 nm。红外反射光谱显示对应于CuO光学声子模式的单个反射峰,并且证实在两个基板上仅存在CuO组成。由光透射率测量计算出的在玻璃基板上生长的CuO膜的光学直接带隙能量为1.37eV。最后,发现所沉积的CuO膜是电阻性的,并且钯形成玻璃上的CuO的欧姆接触和Si上的CuO的肖特基接触。

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