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Biodegradation of Palm-based 9,10-Dihydroxystearic Acid (DHSA)udin aquatic environments

机译:棕榈基9,10-二羟基硬脂酸(DHSA)的生物降解在水生环境中

摘要

Palm-based DHSA is a new chemical developed in MPOB that has three reactive sites that would enable the preparation of many useful derivatives. New chemicals introduced into the market have to be registered and information on their environmental performance such as biodegradability has to be supplied as required under various national and international laws. Biodegradability screening tests, such as the OECD 301 series, are basic tools for assessment of the environmental fate of chemicals in aquatic environments. A substance is considered readily biodegradable when its biodegradability reaches the pass levels of 60% carbon dioxide (CO2)/theoretical carbon dioxide (ThCO2) evolution, 60% biochemical oxygen demand (BOD)/theoretical oxygen demand (ThOD) or 70% dissolved organic carbon (DOC) removal within 28 days. Palm-based DHSA was found to be readily biodegradable where its biodegradability reached 65% within 28 days test period determined via the OECD 301C Modified MITI (I) test method, which passed the 60% level of BOD/ThOD requirement as stipulated in the OECD Guidelines for testing of chemicals. This result is indicative of DHSA’s rapid degradation in aquatic environments. Hence, DHSA is not expected to accumulate in the food chains and will not pose problems in the aquatic environments although it is poorly soluble in water.
机译:基于棕榈的DHSA是MPOB中开发的一种新化学品,具有三个反应位点,可以制备许多有用的衍生物。引入市场的新化学品必须进行注册,并且必须根据各种国家和国际法律的要求提供有关其环境绩效(例如生物降解性)的信息。生物降解性筛选测试,例如OECD 301系列,是评估水生环境中化学品环境命运的基本工具。当某种物质的生物降解能力达到60%二氧化碳(CO2)/理论二氧化碳(ThCO2)释放,60%生化需氧量(BOD)/理论需氧量(ThOD)或70%溶解有机物的通过水平时,就认为该物质易于生物降解。在28天内清除碳(DOC)。通过OECD 301C改良的MITI(I)测试方法确定,其基于棕榈的DHSA在28天内的生物降解性达到了65%时,其生物降解性易于生物降解,该方法通过了OECD规定的BOD / ThOD要求水平的60%化学品测试指南。这一结果表明DHSA在水生环境中迅速降解。因此,尽管DHSA难溶于水,但预计不会在食物链中积累,也不会在水生环境中造成问题。

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