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Study of the Influence of the Almond Shell Variety on the Mechanical Properties of Starch-Based Polymer Biocomposites

机译:杏仁壳种对淀粉基聚合物生物复合材料力学性能影响的研究

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摘要

This article is focused on the development of a series of biodegradable and eco-friendly biocomposites based on starch polymer (Mater-Bi DI01A) filled with 30 wt% almond shell (AS) of different varieties (Desmayo Rojo, Largueta, Marcona, Mollar, and a commercial mixture of varieties) to study the influence of almond variety in the properties of injected biodegradable parts. The different AS varieties are analysed by means of Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), Scanning Electron Microscopy (SEM), and X-ray Diffraction (XRD). The biocomposites are prepared in a twin-screw extruder and characterized in terms of their mechanical (tensile, flexural, Charpy impact, and hardness tests) and thermal properties (differential scanning calorimetry (DSC) and TGA). Despite observing differences in the chemical composition of the individual varieties with respect to the commercial mixture, the results obtained from the mechanical characterisation of the biocomposites do not present significant differences between the diverse varieties used. From these results, it was concluded that the most recommended option is to work with the commercial mixture of almond shell varieties, as it is easier and cheaper to acquire.
机译:本文专注于基于淀粉聚合物(Mater-Bi Di01a)的一系列可生物降解和生态友好的生物复合材料的开发,其填充有30wt%杏仁壳(AS)的不同品种(Desmayo Rojo,Largueta,Marcona,Mollar,和品种的商业混合物)研究杏仁品种在注射可生物降解部件的性质中的影响。通过傅里叶变换红外光谱(FT-IR),热重分析(TGA),扫描电子显微镜(SEM)和X射线衍射(XRD)分析不同的品种。生物复合材料在双螺杆挤出机中制备,其特征在于它们的机械(拉伸,弯曲,夏比碰撞和硬度测试)和热性质(差示扫描量热法(DSC)和TGA)。尽管观察了各种品种的化学成分相对于商业混合物的化学成分差异,但从生物复合材料的机械表征获得的结果并未在所使用的各种品种之间存在显着差异。从这些结果来看,得出结论是,最推荐的选择是使用杏仁壳品种的商业混合物,因为收购更容易和更便宜。

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