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Thermal and Quasi-Static Mechanical Characterization of Polyamide 6-Graphene Nanoplatelets Composites

机译:聚酰胺6-石墨烯纳米层复合材料的热和准静态力学表征

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摘要

The growing demand for lightweight and multifunctional products in numerous industrial fields has recently fuelled a growing interest in the development of materials based on polymer matrices including graphene-like particles, intrinsically characterized by outstanding mechanical, thermal, and electrical properties. Specifically, with regard to one of the main mass sectors, which is the automotive, there has been a significant increase in the use of reinforced polyamides for underhood applications and fuel systems thanks to their thermal and chemical resistance. In this frame, polyamide 6 (PA6) composites filled with graphene nanoplatelets (GNPs) were obtained by melt-compounding and compared in terms of thermal and mechanical properties with the neat matrix processed under the same condition. The results of the experimental tests have shown that the formulations studied so far offer slight improvements in terms of thermal stability but much more appreciable benefits regarding both tensile and flexural parameters with respect to the reference material. Among these effects, the influence of the filler content on the strength parameter is noteworthy. However, the predictable worsening of the graphene sheet dispersion for GNPs contents greater than 3%, as witnessed by scanning electron images of the tensile fractured sections of specimens, affected the ultimate performance of the more concentrated formulation.
机译:众多工业领域的轻质和多功能产品的需求不断增长,最近促进了基于具有石墨烯颗粒的高分子矩阵的材料的发展兴趣,本质上以突出的机械,热和电性能为特征。具体地,关于作为汽车的主要质量扇区之一,由于其热和耐化学性,使用增强聚酰胺和燃料系统的使用具有显着增加。在该框架中,通过熔融配混地获得填充有石墨烯纳米键(GNPS)的聚酰胺6(PA6)复合材料,并在与相同条件下加工的整齐基质的热和机械性能进行比较。实验试验的结果表明,研究到目前为止所研究的配方在热稳定性方面提供微小的改进,但对于参考材料的拉伸和弯曲参数的抗拉和弯曲参数具有更高的可观益处。在这些效果中,填料含量对强度参数的影响是值得注意的。然而,通过扫描样品张力部分的扫描电子图像的扫描电子图像,可预测的GNPS含量的可预测恶化的GNPS含量大于3%,影响了更浓缩的配方的最终性能。

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