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Divergent Reactivity during the Trapping of Benzynes by Glycidol Analogs: Ring Cleavage via Pinacol-Like Rearrangements vs Oxirane Fragmentations

机译：通过糖苷醇类似物捕获苯苄酯期间的发散反应性：通过皮卡糖醇重排的环切割与氧铝碎片

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1. Divergent Reactivity during the Trapping of Benzynes by Glycidol Analogs: Ring Cleavage via Pinacol-Like Rearrangements vs Oxirane Fragmentations [J] . Zhang Juntian, Hoye Thomas R. Organic letters . 2019,第8期

机译：通过糖苷醇类似物捕获苯苄酯期间的发散反应性：通过皮卡糖醇重排的环切割与氧铝碎片
2. Tactics for probing aryne reactivity: mechanistic studies of silicon-oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers [J] . Thomas R. Hoye, Beeraiah Baire, Tao Wang Chemical science . 2014,第2期

机译：探测芳烃反应性的策略：甲硅烷基醚捕获（HDDA生成的）苯炔的过程中硅-氧键裂解的机理研究
3. Tactics for probing aryne reactivity: mechanistic studies of silicon-oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers [J] . Thomas R. Hoye, Beeraiah Baire, Tao Wang Chemical science . 2014,第2期

机译：探测芳烃反应性的策略：甲硅烷基醚捕获（HDDA生成的）苯炔的过程中硅-氧键裂解的机理研究
4. CID Fragmentation Rearrangement of Buspirone Confirmed by LTQ-Orbitrap FT Mass Spectrometer [C] . Austin C. Li, Xingyu Jiang ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：通过LTQ-orbitrap FT质谱仪证实BUSPIRONE的CID碎片重新排列
5. 1. Studies directed toward the synthesis of 20B-carbachaparrinone analogs via a samarium (II) iodide ring closure of a highly functionalized intermediate. 2. Synthesis of 5-oxo-cyclopent-1-enecarboxylic acid methyl esters via a novel tandem aldol-knoevenagel condensation. 3. Novel carbocyclic ring formation via intramolecular enol trapping of an allyl cation in acidic polar media. [D] . DeSelms, Robert Herschel. 2002

机译：1.研究针对通过高度官能化中间体的碘化sa（II）闭环合成20B-氨基苯甲酰吗啉酮类似物。 2.通过新型串联的羟醛-knoevenagel缩合合成5-氧代-环戊-1-烯羧酸甲酯。 3.通过在酸性极性介质中烯丙基阳离子的分子内烯醇捕获而形成新的碳环。
6. Tactics for Probing Aryne Reactivity: Mechanistic Studies of Silicon-oxygen Bond Cleavage During the Trapping of (HDDA-generated) Benzynes by Silyl Ethers [O] . Thomas R. Hoye, Beeraiah Baire, Tao Wang -1

机译：探测Aryne反应性的策略：甲硅烷基醚诱捕（HDDA生成的）苯甲酮过程中硅-氧键裂解的机理研究。
7. Diphosphine Isomerization and C-H and P-C Bond Cleavage Reactivity in the Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne-Substituted Cluster HOs3(CO)8(m3-C6H4)m2, h1-PPhCdC(PPh2)C(O)CH2C(O) [O] . -1

机译：二膦异构化和CH和CH和PC粘合切割反应性在TrioSmium簇OS3（CO）10（BPCD）中：动力学和同位素数据，用于桥接的可逆正交和X射线结构和OS3（CO）10（BPCD）的螯合异构体（BPCD）和苯并替代的簇Hos3（CO）8（M3-C6H4）M2，H1-PPHCDC（PPH2）C（O）CH 2 C（O）
8. Chemistry of the 1,2-Dioxetane Ring System. Chemiluminescence, Fragmentations, and Catalyzed Rearrangements. [R] . Horn, K. A., Schmidt, S. P., Koo, J., 1978

机译：1,2-二氧杂环丁烷环系的化学。化学发光，片段化和催化重排。

Divergent Reactivity during the Trapping of Benzynes by Glycidol Analogs: Ring Cleavage via Pinacol-Like Rearrangements vs Oxirane Fragmentations

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