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Fabrication of surface-functionalized PUA composites to achieve superhydrophobicity

机译:表面官能化的PUA复合材料的制备实现超疏水性

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摘要

Abstract Herein, we present a facile fabrication method to prepare the optically transparent, flexible and self-cleanable poly(urethane acrylate) (PUA) superhydrophobic film. The low surface energy siloxane functionalization on the thermally activated µ-patterned PUA/graphene oxide composite (S-PG) was found to be a successful strategy to modify the PUA intrinsic hydrophilicity into superhydrophobic nature. The S-PG film (with GO content of 0.1 wt%) repeatedly showed the water contact angle (WCA) of 149.82 ± 1° with excellent self-cleaning property. Further, the fabricated film exhibited high optical transparency (80%) in the 400–800 nm wavelength region. Finally, the practical applicability of the fabricated S-PG film was demonstrated by using the film as a protective layer for solar panel module. The power conversion efficiency (PCE) of the solar module with and without S-PG superhydrophobic film was found to be 5.98% and 5.82%, respectively. The enhancement in the PCE performance of the solar module is attributed to the excellent optical transparent and less light reflecting nature of the proposed film.
机译:摘要在本文中,我们提出了一种容易制造方法,制备光学透明,柔性和可自清洁的聚(氨基甲酸酯丙烯酸酯)(PUA)超疏水膜。发现在热活化的μ形状的PUA /石墨烯氧化物复合物(S-PG)上的低表面能硅氧烷官能化是将PUA固有的亲水性改性到超疏水性质的成功策略。 S-Pg膜(具有0.1wt%的GO含量)反复显示水接触角(WCA)为149.82±1°,具有优异的自清洁性能。此外,制造的薄膜在400-800nm波长区域中表现出高光学透明度(80%)。最后,通过使用薄膜作为太阳能电池板模块的保护层来证明制造的S-PG膜的实际适用性。没有S-PG超疏水膜的太阳能模块的电力转换效率(PCE)分别为5.98%和5.82%。太阳能模块的PCE性能的增强归因于所提出的薄膜的优异光学透明和较少的光反射性质。

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