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Effect of Rare-Earth Additions on the Texture of Wrought Magnesium Alloys: The Role of Grain Boundary Segregation

机译:稀土增加对锻造镁合金纹理的影响:晶界偏析的作用

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摘要

Magnesium alloys that contain certain rare-earth(RE) additions are known to have improved formability and this can be partly attributed to the different texture they display after recrystallisation. Previous experimental work has identified segregation of RE to grain boundaries and dislocations as being potentially important in producing this change in behaviour. In the present paper, two classical models (Langmuir-McClean and Cahn Lucke Stuwe) are used to explore the likely effect of RE additions on grain boundary solute concentration and drag. It is demonstrated that a wide range of RE elements are predicted to segregate strongly to grain boundaries due to the large atomic size misfit with magne- sium. The maximum level of segregation is produced for elements such as Y or Gd that combine a high misfit and high bulk solubility. Segregated Y is predicted to produce a solute drag pressure on migrating boundaries several orders of magnitude greater than that obtained by Al or Zn additions. It is demonstrated that whilst this drag is predicted to be insufficient to strongly retard static recrystallisation under typical annealing conditions, it is expected to suppress dynamic recrystallisation (DRX) by any mechanism requiring boundary migration.
机译:已知含有某些稀土(RE)添加的镁合金具有改善的可成形性,并且这可以部分地归因于在重结晶后显示的不同质地。以前的实验工作已经确定了重新缩写和脱位的偏析,因为在产生这种行为变化方面可能是重要的。在本文中,两种古典模型(Langmuir-McClean和Cahn Lucke Stuwe)用于探讨重新添加对晶界溶质浓度和阻力的可能影响。结果证明,由于具有磁性的大原子尺寸不足,预测广泛的重新元素被强烈地分离到晶界。为y或Gd等元素产生的最大偏析水平,其结合高错配和高散装溶解度。预测偏析Y在迁移边界上产生溶质阻力,几个数量级大于通过Al或Zn添加量获得的数量级。结果证明,当该阻力预计不足以在典型的退火条件下强烈延迟静态重结晶,预计通过需要边界迁移的任何机制抑制动态重结晶(DRX)。

著录项

  • 作者

    Joseph D. Robson;

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  • 年度 2013
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  • 原文格式 PDF
  • 正文语种 eng
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