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High-temperature pyrolysis modeling of a thermally thick biomass particle based on an MD-derived tar cracking model

机译：基于MD衍生焦油裂解模型的热厚生物量粒子的高温热解模拟

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Tao Chen; Xiaoke Ku; Tian Li; Bodil S.A. Karlsson; Jonas Sjöblom; Henrik Ström;
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1. New Pyrolysis Model for Biomass Particles in a Thermally Thick Regime [J] . Chen Tao, Ku Xiaoke, Lin Jianzhong, Energy & fuels . 2018,第9期

机译：热浓厚条件下生物质颗粒的新热解模型
2. Finite element modeling of intraparticle heterogeneous tar conversion during pyrolysis of woody biomass particles [J] . Shi Xiaogang, Ronsse Frederik, Pieters Jan G. Fuel Processing Technology . 2016,第Null期

机译：木质生物质颗粒热解过程中颗粒内异质焦油转化的有限元模拟
3. Pyrolysis Simulation of Thermally Thick Biomass Particles Based on a Multistep Kinetic Scheme [J] . Energy & fuels . 2020,第2期

机译：基于多步动力学方案的热浓生物质颗粒热解模拟
4. CATALYTIC CRACKING OF BIOMASS TARS: A MODEL-STUDY OF NAPHTALENE CRACKING WITH MINERAL BASED CATALYSTS [C] . Charlotte Parsland, Michael Strand European biomass conference . 2010

机译：生物质催化裂化：基于矿物的萘裂化萘的模型研究
5. A component based model for the prediction of the product yields of the pyrolysis of a biomass particle. [D] . Eberly, Brian C. 2010

机译：基于组件的模型，用于预测生物质颗粒的热解产物收率。
6. Comparative pyrolysis kinetics of various biomasses based on model-free and DAEM approaches improved with numerical optimization procedure [O] . Miloš Radojević, Bojan Janković, Vladimir Jovanović, 2012

机译：基于无模型和DAEM方法的各种生物质的比较热解动力学通过数值优化程序得到改善
7. This article presents a new numerical model describing the behaviour of a thermally thick wood sample exposed to high solar heat flux (above 1 MW/m2). A preliminary study based on dimensionless numbers is used to classify the problem and support model building assumptions. Then, a model based on mass, momentum and energy balance equations is proposed. These equations are coupled with liquid-vapour drying model and pseudo species biomass degradation model. By comparing to a former experimental study, preliminary results have shown that these equations are not enough to accurately predict biomass behaviour under high solar heat flux. Indeed, a char layer acting as radiative shield forms on the sample exposed surface. In addition to this classical set of equations, it is mandatory to take into account radiation penetration into the medium. Furthermore, as biomass contains water, medium deformation consecutively to char steam gasification must also be implemented. Finally, with the addition of these two strategies, the model is able to properly capture the degradation of biomass when exposed to high radiative heat flux over a range of sample initial moisture content. Additional insights of biomass behaviour under high solar heat flux were also derived. Drying, pyrolysis and gasification fronts are present at the same time inside of the sample. The coexistence of these three thermochemical fronts leads to char gasification by the steam produced from drying of the sample, which it is the main phenomenon behind medium ablation. [O] . Pozzobon, Victor, Salvador, Sylvain, Bézian, Jean Jacques 2018

机译：本文提供了一个新的数值模型，该模型描述了暴露于高太阳热通量（高于1 / MW / m2）的热厚木材样品的行为。基于无量纲数的初步研究用于对问题进行分类并支持模型构建假设。然后，提出了一种基于质量，动量和能量平衡方程的模型。这些方程式与液体蒸汽干燥模型和假物种生物质降解模型耦合。通过与以前的实验研究进行比较，初步结果表明，这些方程不足以准确预测高太阳热通量下的生物量行为。的确，在样品暴露的表面上形成了充当辐射屏蔽层的炭层。除了这套经典的方程式之外，还必须考虑到辐射向介质的渗透。此外，由于生物质中含有水，因此还必须在炭蒸气汽化后进行连续的介质变形。最后，通过添加这两种策略，该模型能够在一定范围的样品初始水分含量下暴露于高辐射热通量的情况下，正确捕获生物质的降解。还得出了在高太阳热通量下生物量行为的其他见解。样品内部同时存在干燥，热解和气化前沿。这三个热化学前沿的共存会导致样品干燥产生的蒸汽产生焦炭气化，这是介质烧蚀的主要现象。
8. Decomposition of tar in pyrolysis gas by partial oxidation and thermal cracking. Part 2 [R] . Brandt, P. , Henriksen, U. 1998

机译：部分氧化和热裂解分解热解气中的焦油。第2部分

High-temperature pyrolysis modeling of a thermally thick biomass particle based on an MD-derived tar cracking model

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