Electrical double layer and electrochemical characteristics at the nanoporousudcarbon | (C₂H₅)₄NBF₄ +acetonitrile interface have been studied byudthe cyclic voltammetry and impedance spectroscopy methods. The valueudof zero charge potential (0.23 V vs. SCE in H₂O), the region of ideal polarizabilityudand other characteristics have been established. Analysis of complexudplane plots shows that the nanoporous carbon | x M (C₂H₅)₄NBF₄ +udacetonitrile interface can be simulated by the equivalent circuit, in whichudthe two parallel conduction parts in the solid and liquid phases are interconnectedudby the double layer capacitance in parallel with the complexudadmittance of hindered reaction of the charge transfer process. The valuesudof the characteristic frequency depend on the electrolyte concentration andudon the electrode potential, i.e. on the nature of ions adsorbed at the surfaceudof nanoporous carbon electrode.
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机译：纳米多孔 udcarbon的双电层和电化学特性用循环伏安法和阻抗谱法研究了（C 2 H 5）₄NBF3 +乙腈的界面。已经建立了零电荷电势的值 ud（在H 2 O中为0.23 V vs. SCE），理想极化率的区域 ud以及其他特性。复杂平面图的分析表明，纳米多孔碳x M（C 2 H 3）₄NBF₄+ 乙腈的界面可以用等效电路来模拟，其中 ud固相和液相的两个平行导电部分相互连接 ud与双层电容并联，与受阻反应的复杂性并联费用转移过程。特征频率的值取决于电解质浓度和电极电势，即取决于吸附在纳米多孔碳电极表面上的离子的性质。
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