A mixture of polyhedral oligosilsesquioxanes containing isocyanate groups in the organic shell of a silsesquioxane core (РOSS-NCO) is synthesized by the reaction of a mixture of polyhedral oli-gosilsesquioxanes with tertiary amine, primary and secondary hydroxylic groups in the organic part of the molecule (РOSS-M) with excess of tolulene diisocyanate. Its derivative is obtained by the reaction of РOSS-NCO with N,N-dimethylaminoethanol. The structure of the synthesized compounds is characterized by GPC, ¹H NMR, and IR spectroscopy.
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机译:在倍半硅氧烷核心(РOSS-NCO)的有机壳中含有异氰酸酯基的多面体低聚倍半硅氧烷的混合物是通过将多面体低聚倍半硅氧烷的混合物与分子有机部分中的叔胺,伯羟基和仲羟基基团反应而合成的(РOSS-M)与过量的甲苯二异氰酸酯。它的衍生物是由РOSS-NCO与N,N-二甲基氨基乙醇反应制得的。合成的化合物的结构通过GPC,1 H NMR和IR光谱表征。
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