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Mitigation of Lost Circulation in Oil-Based Drilling Fluids Using Oil Absorbent Polymers

机译:利用吸油聚合物减缓油基钻井液中丧失循环

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摘要

In order to mitigate the loss circulation of oil-based drilling fluids (OBDFs), an oil-absorbent polymer (OAP) composed by methylmethacrylate (MMA), butyl acrylate (BA), and hexadecyl methacrylate (HMA) was synthesized by suspension polymerization and characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and scanning electronic microscopy (SEM). The oil-absorptive capacity of OAP under different solvents was measured as the function of temperature and time. The effect of the OAP on the rheological and filtration properties of OBDFs was initially evaluated, and then the sealing property of OAP particles as lost circulation materials (LCMs) was examined by a high-temperature and high-pressure (HTHP) filtration test, a sand bed filtration test, a permeable plugging test, and a fracture sealing testing. The test results indicated that the addition of OAP had relatively little influence on the rheological properties of OBDF at content lower than 1.5 w/v % but increased the fluid viscosity remarkably at content higher than 3 w/v %. It could reduce the HTHP filtration and improve the sealing capacity of OBDF significantly. In the sealing treatment, after addition into the OBDF, the OAP particles could absorb oil accompanied with volume enlargement, which led to the increase of the fluid viscosity and slowing down of the fluid loss speed. The swelled and deformable OAP particles could be squeezed into the micro-fractures with self-adoption and seal the loss channel. More important, fluid loss was dramatically reduced when OAP particles were combined with other conventional LCMs by a synergistic effect.
机译:为了减轻油基钻井液(OBDF)的损耗循环(OBDF),通过悬浮聚合和悬浮聚合合成由甲基丙烯酸甲酯(MMA),丙烯酸丁酯(Ba)和十六烷基丙烯酸叔丁酯(HMA)组成的吸油聚合物(OAP)。特征在于傅里叶变换红外光谱(FT-IR),热重分析(TGA)和扫描电子显微镜(SEM)。测量不同溶剂下OAP的油吸收能力作为温度和时间的函数。最初评价OAP对OBDFS流变和过滤性质的影响,然后通过高温和高压(HTHP)过滤试验,通过高温和高压(HTHP),a,然后通过高温和高压(HTHP)过滤试验来评价OBDF的流变和过滤性能的影响。砂床过滤测试,可渗透堵塞测试,以及断裂的密封测试。测试结果表明,oap的添加对低于1.5w / v%的obdf的流变性能影响较小,但在高于3w / v%的含量下显着增加流体粘度。它可以减少HTHP过滤,并显着提高欧多的密封能力。在密封处理中,在加入OBDF之后,OAP颗粒可以吸收伴随体积扩大的油,这导致流体粘度的增加并减慢了流体损失速度。可以通过自采用和密封损耗通道挤压膨胀和可变形的OAP颗粒挤压到微骨折中。更重要的是,通过协同效应与其他常规LCMS与其他常规LCM合并时,流体损失显着降低。

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