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Carbon-Nitrogen Bond Fission in Ureas and Thioureas. Preparation of Alkyl and Aryl Isothiocyanates Using Carbon Bisulfide and Butyllithinm or a Grignard Reagent

机译：脲和硫脲中的碳氮键裂解。使用碳双硫化物和丁基硫脲或GRIGNARD试剂制备烷基和芳基异硫氰酸酯的制备

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作者
Shizuyoshi Sakai; Tatsuo Fujinami; Toshiyuki Aizawa;
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年度 1977
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1. Cross-Coupling of Grignard Reagents with Sulfonyl-Activated sp Carbon-Nitrogen Bonds [J] . Man-Bo Li, Xiang-Ling Tang, Shi-Kai Tian Advanced synthesis & catalysis . 2011 ,第11a12期

机译：格氏试剂与磺酰基活化的sp碳氮键的交叉偶联
2. Nickel catalyzed cross-coupling of modified alkyl and alkenyl Grignard reagents with aryl-and heteroaryl nitriles: activation of the C-CN bond [J] . Joseph A.Miller, John W.Dankwardt Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003 ,第9期

机译：镍催化的修饰烷基和烯基格氏试剂与芳基和杂芳基腈的交叉偶联：C-CN键的活化
3. Practical one-pot preparation of ketones from aryl and alkyl bromides with aldehydes and DIH via Grignard reagents [J] . Dohi S., Moriyama K., Togo H. Tetrahedron . 2012 ,第32期

机译：实用的一锅法通过格氏试剂由芳基和烷基溴化物与醛和DIH制备酮
4. Synthesis of Onium-ferrate Salts and Their Application to the Cross-coupling of Alkyl Halides with Aryl Grignard Reagents [C] . Tsubasa Maruyama, Toru Hashimoto, Yoshitaka Yamaguchi 日本化学会春季年会講演予稿集 . 2018

机译：用芳基格氏试剂的烷基卤化物交叉偶联的甘露酸酯盐的合成及其应用
5. 1. Reduction of Tertiary Benzamides to Benzaldehydes by an in situ-Generated Schwartz Reagent (Cp2 Zirconium (Hydrogen)Chloride); Formal Synthesis of Lysergic Acid. 2. Ru-Catalyzed Amide-Directed Aryl Carbon-Hydrogen, Carbon-Nitrogen and Carbon-Oxygen Bond Functionalizations: C-B Formation, Carbon-Carbon Suzuki Cross Coupling and Hydrodemethoxylation [D] . Zhao, Yigang 2011

机译：1.通过原位生成的Schwartz试剂（Cp2氯化锆（氢）氯化物）将叔苄酰胺还原为苯甲醛；麦角酸的正式合成。 2. Ru催化的酰胺基芳烃碳氢，碳氮和碳氧键功能化：C-B形成，碳-碳铃木交叉偶联和加氢脱甲氧基化
6. Iron-Catalyzed C(sp2)–C(sp3) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents [O] . Elwira Bisz, Michal Szostak 2020

机译：铁催化芳基氯苯甲酸酯与烷基格氏试剂的C（sp2）–C（sp3）交叉偶联
7. SELECTIVE FORMATION OF KETONE, DIKETONE AND ALDEHYDE BY THE CO INSERTION INTO NICKEL–ALKYL BONDS OF DIALKYLNICKEL COMPLEXES. A NOVEL NICKEL-CATALYZED SYNTHESES OF KETONES AND TERTIARY ALCOHOLS FROM GRIGNARD REAGENTS, ARYL HALIDES, AND CARBON MONOXIDE [O] . Takakazu Yamamoto, Teiji Kohara, Akio Yamamoto 1976

机译：CO插入二烷基尼克尔配合物的镍烷基键，选择性地形成酮，二酮和醛。一种新的镍催化的酮和来自格氏试剂，芳基和一氧化碳的叔醇的合成
8. Mechanism of the Reaction between Alkyl- and Aryl Grignard Reagents and Hexachlorocyclotriphosphazene: An Explanation of Bi(Cyclophosphazene Formation). [R] . Allcock, H. R., Desorcie, J. L., Harris, P. J. 1982

机译：烷基 - 和芳基格氏试剂与六氯环三磷腈反应的机理：Bi（环磷腈形成）的解释。

Carbon-Nitrogen Bond Fission in Ureas and Thioureas. Preparation of Alkyl and Aryl Isothiocyanates Using Carbon Bisulfide and Butyllithinm or a Grignard Reagent

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