首页> 外文OA文献 >Facile C-H Bond Activation: Synthesis of the N4C Donor Set Pentadentate Ligand 1, 4-Bis(2-pyridylmethyl)-1, 4-diazacyclononane (dmpdacn) and a Structural Study of Its Alkyl-Cobalt(III) Complex Co(dmpdacn-C)(OH2)(ClO4)2H2O and Its Hydroxylated Derivative Co(dmpdacnOH-O)Cl(ClO4)2C3H6O

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Facile C-H Bond Activation: Synthesis of the N4C Donor Set Pentadentate Ligand 1, 4-Bis(2-pyridylmethyl)-1, 4-diazacyclononane (dmpdacn) and a Structural Study of Its Alkyl-Cobalt(III) Complex Co(dmpdacn-C)(OH2)(ClO4)2H2O and Its Hydroxylated Derivative Co(dmpdacnOH-O)Cl(ClO4)2C3H6O

机译：Facile CH键活化：N4C供体置的合成戊酸配体1,4-双（2-吡啶基甲基）-1,4-二氮酰基（DMPDACN）和其烷基 - 钴（III）复合物的结构研究CO（DMPDACN- C）（OH2）（CLO 4）2H 2 O及其羟基化衍生物CO（DMPDACNOH-O）CL（CLO4）2C36O

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1. Facile C-H bond activation: Synthesis of the N4C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl-cobalt(III) complex [Co(dmpdacn-C)(OH2)](ClO4)(2)center dot H2O and its hydroxy [J] . Zhou XT, Day AI, Edwards AJ, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第2期

机译：简便的CH键活化：N4C供体组五齿配体1,4-双（2-吡啶甲基）-1,4-二氮杂环壬烷（dmpdacn）的合成及其烷基-钴（III）配合物[Co（dmpdacn- C）（OH2）]（ClO4）（2）中心点H2O及其羟基
2. Synthesis and characterization of the pentadentate macrobicyclic ligand, 14-thia-1,4,8,11-tetraazabicyclo[9.5.3]nonadecane (L1) and its nickel(II) complexes. X-ray crystal structure of [Ni(L1)(ClO4)](ClO4)center dot 2[Ni(L1)(OH2)](ClO4)(2)center dot [J] . Coulter KR., Rettig S., McAuley A. Canadian Journal of Chemistry . 2001,第5期

机译：五齿大双环配体，14-thia-1,4,8,11-四氮杂双环[9.5.3]十八碳烯（L1）及其镍（II）配合物的合成与表征。 [Ni（L1）（ClO4）]（ClO4）中心点2 [Ni（L1）（OH2）]（ClO4）（2）中心点的X射线晶体结构
3. Cobalt-mediated selective C-H bond activation. Direct aromatic hydroxylation in the complexes [Co-III{o-OC6H3(R)N=NC5H4N}(2)]ClO4 center dot H2O (R = H, o-Me/Cl, m-Me/Cl or p-Me/Cl). Synthesis, spectroscopic and redox properties [J] . Bharath A., Munshi P., Lahiri GK., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第16期

机译：钴介导的选择性C-H键活化。配合物[Co-III {o-OC6H3（R）N = NC5H4N}（2）] ClO4中心点H2O的直接芳族羟基化（R = H，o-Me / Cl，m-Me / Cl或p-Me / Cl）。合成，光谱和氧化还原性质
4. Synthesis, Reactivity, and DFT Studies of Tantalum Complexes Incorporating Diamido-N-heterocyclic Carbene Ligands. Facile Endocyclic C-H Bond Activation [O] . -1

机译：钽配合物的合成，反应性和DFT研究掺入二酰胺-N-杂环碳配体。容易内环C-H键活化

Facile C-H Bond Activation: Synthesis of the N4C Donor Set Pentadentate Ligand 1, 4-Bis(2-pyridylmethyl)-1, 4-diazacyclononane (dmpdacn) and a Structural Study of Its Alkyl-Cobalt(III) Complex Co(dmpdacn-C)(OH2)(ClO4)2H2O and Its Hydroxylated Derivative Co(dmpdacnOH-O)Cl(ClO4)2C3H6O

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