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Accelerated aging of WPCs Based on Polypropylene and Birch plywood Sanding Dust

机译:基于聚丙烯和桦木胶合板砂光粉尘的WPC衰老加速

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摘要

A lot of researchers are closely related with natural, lignocellulose fibre containing bio-composites production and studies. Various of polymer matrices, mainly polyolefins, combinations with natural fibres as a reinforcement are used. Our studies are focused on polypropylene based bio-composites containing birch plywood production by-product sanding dust (PSD) accelerated weathering processes. The obtained results showed the following sight. After the aging the surface of all samples had faded, the changes of the gloss (decreasing) and of the whiteness degree (increasing) also had taken place, but microhardness of the surface of specimens significantly has decreased. The tensile strength and modulus of the samples after UV aging diminished about 30–35%. That indicates to the changes not only in the surface layers of polymer but also inside of the polymer structure. The FTIR measurements showed that during UV aging process occurs significant changes of chemical structure of the weathered surface of all samples. DSC measurements showed an increase of degree of crystallinity of the weathered polypropylene composites after the first heating due to the recrystallization process in the polypropylene matrix and a small decreasing after second heating. The melting temperatures of all composites after UV aging considerably diminish up to 30°C.
机译:许多研究人员与含生物复合材料的天然木质纤维素纤维密切相关,含有生物复合材料的生产和研究。使用各种聚合物基质,主要是聚烯烃,与加强件具有天然纤维的组合。我们的研究专注于含有桦木胶合板生产副产物砂粉(PSD)加速风化工艺的聚丙烯基生物复合材料。获得的结果表明以下视觉。在老化后,所有样品的表面褪色,光泽度(减小)和白度度(增加)也发生了变化,但样本表面的微硬度显着降低。 UV老化后样品的拉伸强度和模量减少了约30-35%。这表明不仅在聚合物的表面层中的变化,而且表示在聚合物结构的内部。 FTIR测量结果表明,在紫外线老化过程中,发生了所有样品的风化表面的化学结构的显着变化。 DSC测量显示在第一次加热之后,由于聚丙烯基质中的重结晶方法和第二加热后的小减小,在第一次加热之后,在第一加热之后增加了风化聚丙烯复合材料的结晶度的增加。 UV老化后所有复合材料的熔化温度明显减少到30℃。

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