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Gas phase ligation of U+. Comparison of pyrene, phenanthridine and phenanthrene as ligands

机译:U +的气相连接。 of,菲和菲作为配体的比较

摘要

Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.
机译:将FT ICR MS仪器中的U +与菲的连接与以前的pyr与菲啶在U +上的结果进行了比较。所有研究过的过程都与仪器中的水和氧气痕量与U +氧化竞争。比较表明,氧化优先涉及脱氢的连接产物。

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