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Recent Advances on the Application of Layered Double Hydroxides in Concrete—A Review

机译:近期氢氧化物在混凝土中应用的最新进展 - 评论

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摘要

The issue of chloride induced corrosion of reinforced concrete is a serious problem affecting infrastructure globally and causing huge economic losses. As such this issue has gained a considerable attention in the scientific community in the recent past. Layered Double Hydroxides (LDHs) have recently emerged as a new class of concrete-additives with a potential to increase the chloride resistance of concrete and mitigate corrosion. LDHs are clay like structures consisting of positively charged layers of cations with associated hydroxides and exchangeable anions in between the layers. Due to this charge balanced structure, LDHs possess the property of encapsulating an anion from the environment and replacing it with an exchangeable anion present in its layers. Potential applications include chloride entrapment in concrete and delivery of corrosion inhibiting anions. However, many versatile compositions of LDHs can be easily synthesized and their application as cement additives reach far beyond corrosion mitigation in concrete. This review presents a summary of recent advances on the applications of LDH in concrete. An extensive set of recently published literature has been critically reviewed and trends have been identified.
机译:氯化物诱导的钢筋混凝土腐蚀问题是一个严重的问题,影响全球基础设施,造成巨大的经济损失。由于这种问题在最近的过去的科学界中取得了相当大的关注。最近,层状双氢氧化物(LDHS)最近作为一类新的混凝土添加剂,具有增加混凝土和减轻腐蚀的氯化物抗性。 LDH是粘土,如结构,其结构包括带有相关的氢氧化物的带正电荷的阳离子和层之间的可交换阴离子。由于该电荷平衡结构,LDH具有从环境中封装阴离子的性质,并用其层中存在的可更换的阴离子替换它。潜在的应用包括混凝土中的氯化物抑制和输送腐蚀抑制阴离子。然而,可以容易地合成LDH的许多通用组合物,并且它们作为水泥添加剂的应用远远超出混凝土中的腐蚀缓解。本综述介绍了LDH在混凝土中的应用近期进展的摘要。一系列最近发表的文献受到严重审查,已经确定了趋势。

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