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Comparison and Characterisation of Regenerated Chitosan from 1-Butyl-3-methylimidazolium Chloride and Chitosan from Crab Shells

机译:从螃蟹壳中的1-丁基-3-甲基咪唑氯和壳聚糖的再生壳聚糖的比较与表征

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摘要

Chitosan is a biopolymer derived from chitin which is naturally occurring in the exoskeleton of crustaceans. This paper reports dissolution and regeneration of chitosan by directly dissolving in an ionic liquid solvent, 1-butyl-3-methylimidazolium chloride (BMIMCl). This will provide an ideal platform to solubilise these kinds of polymers to achieve the dissolution. The current study dissolved chitosan from crab shell utilising BMIMCl as a solvent and characterised the resultant regenerated polymer. The regenerated chitosan showed increased hydrogen bonding when characterised by Fourier transform infrared (FTIR) spectral analysis. In addition, the study also compared the characteristics of regenerated and generic chitosan. The regenerated chitosan was also evaluated for antimicrobial properties and showed to possess antibacterial features similar to the commercial grade. This method can be utilised in future for blending of polymers with chitosan in a dissolved phase.
机译:壳聚糖是衍生自甲壳素的生物聚合物,其天然存在于甲壳类动物的外骨架中。本文通过直接溶解在离子液体溶剂,1-丁基-3-甲基咪唑氯化物(BmimCl)中,报告壳聚糖的溶解和再生。这将提供一个理想的平台来溶解这些聚合物以实现溶解。目前的研究用Bmimcl作为溶剂的蟹壳从蟹壳中溶解壳聚糖,并表征所得再生聚合物。当通过傅里叶变换红外(FTIR)光谱分析表征时,再生壳聚糖显示出氢键合。此外,该研究还比较了再生和通用壳聚糖的特征。还评估了再生的壳聚糖用于抗微生物性质,并显示出与商业等级类似的抗菌特征。将来可以使用该方法以将聚合物与壳聚糖在溶解的相中混合。

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