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Influence of Superhydrophobic Coating on the Water Resistance of Foundry Dust/Magnesium Oxychloride Cement Composite

机译:超疏水涂层对铸造粉尘/氯氧化镁水泥复合材料耐水性的影响

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摘要

In this work, magnesium oxychloride cement (MOC) was used to realize the resource use of foundry dust (FD). Portland cement (PC)-based superhydrophobic coating was prepared on the surface of FD/MOC composite to improve the water resistance of the composite. First, the FD/MOC composites with different contents of FD were prepared. The phase structure of the composite was analyzed using X-ray diffraction (XRD). The microstructure of the cross-section and surface of the composite was observed using field emission scanning electron microscope (FE-SEM). The mechanical properties of the FD/MOC composites with different FD contents at different ages were tested and analyzed. Secondly, the superhydrophobic coating was prepared on the surface of MOC composite using silane/siloxane aqueous emulsion as the hydrophobic modifier, PC as the matrix and water as the solvent. The microstructure and chemical composition of the PC-based superhydrophobic coating were tested and analyzed. The results show that FD can significantly improve the early strength of the FD/MOC composite. The 28-day compressive strength of the FD/MOC composite decreases with increasing FD content. When the FD content is 30%, the 28-day compressive strength of the FD/MOC composite is as high as 75.68 MPa. Superhydrophobic coating can effectively improve the water resistance of the FD/MOC composite. The softening coefficient of the FD/MOC composite without superhydrophobic coating is less than 0.26, while that of the composite modified by superhydrophobic coating is greater than 0.81.
机译:在这项工作中,使用氯氧化镁水泥(MOC)来实现铸造粉尘(FD)的资源使用。在FD / MOC复合物表面上制备了基于FD / MOC复合材料的基于外疏水涂层,以改善复合材料的耐水性。首先,制备具有不同FD含量的FD / MOC复合材料。使用X射线衍射(XRD)分析复合物的相结构。使用现场发射扫描电子显微镜(Fe-SEM)观察复合材料横截面和表面的微观结构。测试并分析了不同年龄不同FD含量的FD / MOC复合材料的机械性能。其次,使用硅烷/硅氧烷水性乳液作为疏水改性剂,作为基质和水作为溶剂,在MOC复合物表面上制备超疏水涂层。测试并分析了基于PC的超疏水涂层的微观结构和化学组成。结果表明,FD可以显着提高FD / MOC复合材料的早期强度。 FD / MOC复合材料的28天压缩强度随着FD含量的增加而降低。当FD含量为30%时,FD / MOC复合材料的28天压缩强度高达75.68MPa。超疏水涂层可有效提高FD / MOC复合材料的耐水性。 FD / MOC复合材料的软化系数没有超疏水涂层小于0.26,而通过超疏水涂层改性的复合材料的复合材料大于0.81。

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