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The electromigration effect revisited: non-uniform local tensile stress-driven diffusion

机译:重新介绍了电迁移效应:非均匀的局部拉伸应力驱动扩散

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摘要

Abstract The electromigration (EM) effect involves atomic diffusion of metals under current stressing. Recent theories of EM are based on the unbalanced electrostatic and electron-wind forces exerted on metal ions. However, none of these models have coupled the EM effect and lattice stability. Here, we performed in situ current-stressing experiments for pure Cu strips using synchrotron X-ray diffractometry and scanning electron microscopy and ab initio calculations based on density functional theory. An intrinsic and non-uniform lattice expansion – larger at the cathode and smaller at the anode, is identified induced by the flow of electrons. If this electron flow-induced strain is small, it causes an elastic deformation; while if it is larger than the yield point, diffusion as local stress relaxation will cause the formation of hillocks and voids as well as EM-induced failure. The fundamental driving force for the electromigration effect is elucidated and validated with experiments.
机译:摘要电迁移(EM)效应涉及金属在电流强调下的原子扩散。 EM的最近理论基于施加在金属离子上的不平衡的静电和电子风力。然而,这些模型中没有任何一部分耦合EM效果和晶格稳定性。这里,我们使用Synchrotron X射线衍射测定和扫描电子显微镜和基于密度泛函理论的扫描电子显微镜和AB Initio计算的纯Cu条对纯Cu条进行的原位电流应力实验。通过电子流识别通过电子流鉴定在阴极处的固有和非均匀的晶格膨胀 - 较大并且在阳极处较小。如果该电子流量诱导的应变小,则引起弹性变形;虽然如果它大于屈服点,但随着局部应力松弛的扩散将导致小丘和空隙的形成以及EM诱导的故障。阐明了电迁移效应的基本驱动力并用实验验证。

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