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The influence of the range of excluded volume interactions on the linear viscoelastic properties of dilute polymer solutions

机译:排斥体积相互作用范围对稀聚度溶液线性粘弹性的影响

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摘要

The Rouse model has recently been modified to take into account the excludedvolume interactions that exist between various parts of a polymer chain byincorporating a narrow Gaussian repulsive potential between pairs of beads onthe Rouse chain (cond-mat/0002448). The narrow Gaussian potential ischaracterized by two parameters: z* - which accounts for the strength of theinteraction, and d* - which accounts for the extent of the interaction. In thelimit of d* going to zero, the narrow Gaussian potential tends to the morecommonly used delta-function repulsive potential. The influence of theparameter d*, in the limit of infinite chain length, on equilibrium and linearviscoelastic properties, and on universal ratios involving these properties, isexamined here. A renormalization group calculation of the end-to-end vectorsuggests that the value chosen for the variable d* will not affect criticalexponents, or universal ratios. A similar trend is also observed for resultsobtained with an approximate solution, which is based on the assumption thatthe non-equilibrium configurational distribution function is Gaussian.
机译:最近通过对Rouse模型进行了修改,以考虑到通过在Rouse链上的成对的小珠之间引入窄的高斯排斥势,而在聚合物链的各个部分之间存在的排除的体积相互作用(cond-mat / 0002448)。窄高斯势的特征在于两个参数:z *-表示相互作用的强度,d *-表示相互作用的程度。在d *的极限为零时,窄高斯势倾向于趋向于更常用的增量函数排斥势。在此检查参数d *在无限链长的范围内对平衡和线性粘弹性质以及涉及这些性质的通用比的影响。端到端向量的重归一化组计算表明,为变量d *选择的值不会影响临界指数或通用比率。对于基于近似解获得的结果,也观察到了类似的趋势,该近似解基于以下假设:非平衡构型分布函数是高斯分布。

著录项

  • 作者

    J. Ravi Prakash;

  • 作者单位
  • 年度 2001
  • 总页数
  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"english","id":9}
  • 中图分类
  • 入库时间 2022-08-20 22:05:35

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