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Influence of the Stabilization System on the Rheological Behaviour of Plasticized PVC for Cables’ Insulation

机译:稳定体系对电缆塑化PVC流变行为的影响

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摘要

The paper is devoted to the rheological study of plasticized PVC - based compositions for cables’ insulation, stabilized with three different systems (Ba laurate/Cd laurate, Sn dibutyl mercaptide, Pb bibasic stearate/Pb bibasic fosfite) in variable ratios. Starting from some measured parameters, several rheological properties - characteristic for the viscous and, respectively, elastic component of flowing - have been calculated (counter pressure, worm gear’s rotation moment, shear stress at the wall, apparent viscosity, standard viscosity and the viscosity index, output pressure from the rheological nozzle, swelling, relaxation time, first function of the normal unitary stresses, index of elasticity). The observation to be made is that the system of thermal stabilization influences strongly the rheological behaviour by both its nature and amount, which requires a careful consideration of the effects, when products of different types are to be designed. The best thermal stabilization is assured by the Pb bibasic stearate/Pb bibasic fosfite - based system. The obtained recipes have been subsequently characterized from the viewpoint of their thermal stability and, equally, of some of their electrical properties. It was observed that the system of thermal stabilization strongly influences the thermal stability as well as the electrical properties of the plasticized PVC recipes. The highest values of thermal stability, which correlated with corresponding electrical properties, have been attained for the Pb- based system. When different stabilization systems are employed, the transparent, translucent or opaque insulations may be obtained.
机译:纸张致力于增塑PVC的流变学 - 基组合物用于电缆绝缘,具有三种不同的系统(BA月桂酸/镉,月桂酸二丁基锡硫醇,二碱式铅硬脂酸酯/二碱式铅fosfite)在可变比率稳定化。从一些测量参数开始,几个流变性质 - 分别为粘性特征,并且,流动​​的弹性元件 - 已经被计算(反压,蜗轮的旋转力矩,在壁剪切应力,表观粘度,标准粘度和粘度指数从流变喷嘴输出压力,肿胀,松弛时间,正常单一应力的第一功能,弹性的指数)。要做出的观察结果是热稳定的系统都通过它的性质和数量,这需要的效果慎重考虑,当不同类型的产品将被设计影响强烈的流变行为。基于系统 - 最佳的热稳定化是由铅二碱式硬脂酸/二碱式铅fosfite放心。将所得到的配方有从它们的热稳定性的观点出发,随后被表征,并且,同样地,他们的一些电特性。据观察,热稳定的系统强烈地影响热稳定性以及增塑PVC配方的电性能。热稳定性的最高值,其与相应的电特性相关的,已经实现了基于PB-系统。当不同的稳定体系中使用,可以得到在透明,半透明或不透明绝缘。

著录项

  • 作者

    Filip Petraru; Marcel Popa;

  • 作者单位
  • 年度 2017
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  • 原文格式 PDF
  • 正文语种 eng
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