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A Comparative Study of Interdigitated Electrode and Quartz Crystal Microbalance Transduction Techniques for Metal–Organic Framework-Based Acetone Sensors

机译:用于金属 - 有机骨架的丙酮传感器的叉抗电极和石英晶微观转导技术的对比研究

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摘要

We present a comparative study of two types of sensor with different transduction techniques but coated with the same sensing material to determine the effect of the transduction mechanism on the sensing performance of sensing a target analyte. For this purpose, interdigitated electrode (IDE)-based capacitors and quartz crystal microbalance (QCM)-based resonators were coated with a zeolitic⁻imidazolate framework (ZIF-8) metal⁻organic framework thin films as the sensing material and applied to the sensing of the volatile organic compound acetone. Cyclic immersion in methanolic precursor solutions technique was used for depositing the ZIF-8 thin films. The sensors were exposed to various acetone concentrations ranging from 5.3 to 26.5 vol % in N2 and characterized/compared for their sensitivity, hysteresis, long-term and short-term stability, selectivity, detection limit, and effect of temperature. Furthermore, the IDE substrates were used for resistive transduction and compared using capacitive transduction.
机译:我们介绍了两种具有不同转导技术的传感器的比较研究,但涂覆了相同的传感材料,以确定转导机制对感测靶分析物的感测性能的影响。为此目的,基于交叉的电极(IDE)的电容(IDE)的电容器和石英晶体微稳定(QCM)的谐振器用沸石蛋白⁻咪唑酯框架(ZIF-8)金属⁻框架薄膜作为传感材料,并施加到感测挥发性有机化合物丙酮。甲醇前体溶液技术循环浸渍用于沉积ZIF-8薄膜。将传感器暴露于N 2中的5.3-26.5体积%的各种丙酮浓度,并表征/比较它们的敏感性,滞后,长期和短期稳定性,选择性,检测极限和温度的影响。此外,使用电容转导的IDE底物用于电阻转导。

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