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Tumbling-Snake Model for Polymeric Liquids Subjected to Biaxial Elongational Flows with a Focus on Planar Elongation

机译:用于对双轴伸长流动的聚合物液体的翻滚模型,重点是平面伸长率

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摘要

We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the presence of both steady-state and transient shear and uniaxial elongational flows, supplemented by a variable link tension coefficient. Here, we provide the transient and stationary solutions of the tumbling-snake model under biaxial elongation both analytically, for small and large elongation rates, and via Brownian dynamics simulations, for the case of planar elongational flow over a wide range of rates, times, and the model parameters. We show that both the steady-state and transient first planar viscosity predictions are similar to their uniaxial counterparts, in accord with recent experimental data. The second planar viscosity seems to behave in all aspects similarly to the shear viscosity, if shear rate is replaced by elongation rate.
机译:我们最近解决了浓缩聚合物溶液的翻滚模型,并在稳态和瞬态剪切和单轴伸长流情况下缠绕熔体,由可变连杆张力系数补充。在这里,我们在分析上,为小型和大的伸长率和大伸长率模拟提供了双轴伸长率下的扭曲蛇模型的瞬态和静止解决方案,以及通过布朗动力学模拟,对于广泛的速率,时间,时间,和模型参数。我们表明,稳态和瞬态的第一个平面粘度预测与最近的实验数据相当于其单轴对应物。如果通过伸长率代替剪切速率,则第二平面粘度似乎同样地表现在剪切粘度的情况下。

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