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The Impacts of Seawater Mg/Ca and Temperature on Element Incorporation in Benthic Foraminiferal Calcite

机译:海水MG / CA和温度对底栖多氨基岩蚁的影响对元素掺入的影响

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摘要

Abstract On geological timescales, oceanic [Mg21] and [Ca21] vary with changing rates of weathering,seafloor spreading and dolomite formation. Accurate reconstruction of the ratio between [Mg21] and[Ca21] in seawater (Mg/Casw), may potentially be reconstructed using foraminiferal Mg/Ca ratios. Since bothtemperature and seawater Mg/Ca impact foraminiferal Mg/Ca, successful reconstruction of Mg/Caswrequires quantification of both these parameters independently on foraminiferal Mg/Ca, as well as theircombined effect on Mg-incorporation. Here we present the combined and isolated impacts of temperatureand Mg/Casw on Mg incorporation in two model species, the benthic hyaline (i.e., perforate) foraminiferElphidium crispum and porcelaneous (i.e., miliolid) foraminifer Quinqueloculina sp. using controlled growthexperiments. Specimens of these two species were kept at four different temperatures (ranging from 10 to278C) and three Mg/Casw’s (3.4, 6.4 and 8.5 mol/mol), resulting in 12 experimental conditions. Newly growncalcite was analyzed for a number of elements (Na, Mg and Sr) by laser ablation-ICP-MS. Results show thatalthough the Mg/Ca varied by more than an order of magnitude between species, the sensitivity of Mgincorporation with respect to temperature appeared not to be influenced by Mg/Casw. By extension, theseresults may also help improving accuracy in the reconstruction of past Mg/Casw based on foraminifera withcontrasting Mg/Ca.
机译:摘要在地质时间尺度,海洋[Mg21]和[CA21]随着风化,海底散布和白云石形成而变化。可以使用Foraminiferal Mg / Ca比来重建跨海水(Mg / casw)在海水(mg / casw)中的比例的精确重建。由于两种温度和海水Mg / Ca冲击火花素Mg / Ca,因此独立地重建Mg / caswrequires的定量,这些参数独立于Foraminiferal mg / ca,以及它们对Mg掺入的影响。在这里,我们在两种模型物种中,介绍了温度掺入的Mg掺入的组合和分离的影响,使透明的透明石(即穿孔)对aminiferlhidium crispum和陶瓷(即miliolid)foraminifer Quinqueloculina sp。使用受控的生长实验。这两种物种的标本保持在四种不同的温度(范围为10-278℃)和三毫克/桶水(3.4,6.4和8.5mol / mol),导致12个实验条件。通过激光烧蚀-ICP-MS分析新生甲酸酯的多种元素(Na,Mg和Sr)。结果表明,虽然Mg / Ca在物种之间的多个数量级变化,但是Mgincoration相对于温度的敏感性出现不受Mg / Casw的影响。通过延伸,该研究还可以帮助提高基于Foraminifera的Forlasting Mg / Ca重建过去的Mg / Casw的精度。

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