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Multiple Shear-Banding Transitions for a Model of Wormlike Micellar Solutions

机译:用于蠕虫胶束溶液模型的多剪切条转换

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摘要

Wormlike micelles are long wormy cylindrical aggregates of surfactants, self-assembled within a solvent, which entangle and continuously break and reform at thermal equilibrium. Rheological characterization and flow visualization experiments with micellar solutions show that under steady state shearing flow the deformation field may not remain homogeneous but instead spatially localize, resulting in the formation of pronounced shear bands. Models which capture this banding behavior generally display a nonmonotonic constitutive response or “flow curve” (of the shear stress resulting from the imposed shear rate). Homogeneous steady state solutions along the decreasing portion of this constitutive curve are unstable and, under shear rate control, the solution in this regime bifurcates to a spatially inhomogeneous flow with two shear rates selected from the positive slope portions of the curve that coexist at identical values of the stress. Tracking of the spatio-temporal development of the banded solution structure shows a strong elastic recoil in the local fluid velocity profile at short times (earlier than the effective relaxation time of the entangled chains). At longer times the velocity profile approaches its steady banded state. These predictions agree with experimental observations by Miller and Rothstein [J. Non-Newtonian Fluid Mech., 143 (2007), pp. 22--37]. In this paper the interplay of the competing roles of inertia, the imposed shear rate, and the transient dynamics of the start up in the flow are examined using the VCM (Vasquez--Cook--McKinley) model. This constitutive model is a scission/reforming network model developed to capture the essential physics of the deformable micellar microstructure and its coupling to the macroscopic flow field. The addition of inertia into the coupled set of nonlinear partial differential equations describing the material response changes the type of the equation set, introducing a transient damped (diffusive and dispersive) inertio-elastic shear wave following the imposition of flow. Depending on the relative time scales associated with the damping, the shear wave speed, the start-up ramp speed, and the imposed shear rate, the reflections of the damped transient wave from the boundaries can interfere with the microscopic mechanisms leading to elastic recoil and the localization of the shear that leads to formation of a shear band. The result of this interference is the establishment of a transient velocity profile with a varying number of (two, three, or four) shear bands. When there is no stress diffusion in the model the multiple-banded profile exists to steady state, and the resulting macroscopic flow is thus not uniquely specified by the imposed shear rate alone.
机译:蜗杆状胶束是长虫圆柱形聚集体的表面活性剂,在溶剂内自组装,其在热平衡时缠绕和连续地破裂和改造。具有胶束溶液的流变表征和流量可视化实验表明,在稳态剪切流下,变形场可以不保持均匀,而是在空间上定位,从而形成明显的剪切带的形成。捕获该条带行为的模型通常显示非单调的组成型响应或“流量曲线”(由施加的剪切速率导致的剪切应力)。沿着该本构曲线的减小部分的均匀稳态解决方案是不稳定的,并且在剪切速率控制下,该制度的溶液在空间不均匀的流动中与两个剪切速率分叉,其选自相同值的曲线的正斜率部分中选择的两个剪切速率压力。跟踪带状溶液结构的时空发展,在短时间内显示出局部流体速度曲线中的强弹性反冲(比缠结链的有效松弛时间)。在较长的时间内,速度曲线接近其稳定的带状状态。这些预测与Miller和Rothstein的实验观察一致[J.非牛顿液体机械。,143(2007),第22-37页.37]。在本文中,使用VCM(vasquez - cook-mckinley)模型来检查惯性竞争作用的相互作用,强加的剪切速率,施加的剪切速率和瞬态动力学。该本构模型是开发的群体/重整网络模型,以捕获可变形胶束组织微观结构的基本物理及其与宏观流场的耦合。将惯性添加到描述材料响应的耦合的非线性偏微分方程中的耦合集合改变了等式集的类型,在施加流动之后引入瞬态阻尼(扩散和分散)惰性剪切波。根据与阻尼相关的相对时间尺度,剪切波速,启动斜坡速度和施加的剪切速率,来自边界的阻尼瞬态波的反射可以干扰导致弹性反冲的显微镜机制剪切的定位导致形成剪切带。这种干扰的结果是建立具有不同数量的(两个,三个或四个)剪切带的瞬态速度曲线。当模型中没有应力扩散时,多条带状的轮廓存在于稳态,因此由此产生的宏观流量不能单独地通过施加的剪切速率唯一地指定。

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