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Reprocessing of artificial UV-weathered wood flour reinforced polypropylene composites

机译:人造紫外线木面粉加强聚丙烯复合材料的再加工

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摘要

This work aims to determine and understand the influence of UV weathering on the reprocessing of a wood-plastic composite (WPC), i.e. of a wood flour reinforced polypropylene (PP) composites. Two wood flour contents (10% w/w and 30% w/w) were studied in comparison with neat PP. Compounds were produced by twin-screw extrusion. Then, ISO1A “dog bone” samples were obtained by injection molding and exposed to an artificial UV weathering using a xenon arc climatic chamber in order to simulate a long-term outdoor exposure. After this weathering stage, photo-degraded samples were submitted to grinding and injection cycles and characterized through different experimental technics. The visual evolution of the surface was followed by optical microscopy and scanning electron microscopy. In order to understand the material physical degradation, the mechanical behavior was measured thanks to tensile, Charpy impact and DMTA (Dynamic Mechanical Thermal Analysis) tests. The assessment of the microstructural evolution was performed by differential scanning calorimetry (crystallinity ratio), size exclusion chromatography (average molecular weights) tests and infrared spectroscopy (chemical structure). Additional rheological tests assessed assumptions on degradation mechanisms.
机译:这项工作旨在确定和理解UV风化对木塑料复合材料(WPC)的再加工的影响,即木粉增强聚丙烯(PP)复合材料。与整齐的PP相比,研究了两种木粉含量(10%w / w和30%w / w)。通过双螺杆挤出制备化合物。然后,通过注射成型获得ISO1A“狗骨”样品,并使用氙弧气候室暴露于人造UV风化,以模拟长期户外曝光。在该耐候性阶段之后,将光化的样品提交到研磨和注射循环,并通过不同的实验技术表征。表面的视觉演变之后是光学显微镜和扫描电子显微镜。为了了解物理降解,由于拉伸,夏比冲击和DMTA(动态机械热分析)测试,测量机械行为。通过差示扫描量热法(结晶度比),尺寸排阻色谱(平均分子量)试验和红外光谱(化学结构)进行微观结构演化的评估。额外的流变试验评估了降解机制的假设。

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