In this study, the effect of the use of different p-n type semiconductor materials in the thermoelectric generator designed to convert the exhaust waste heat energy of the internal combustion engines to electrical energy on the output parameters of the thermoelectric generator (load current, output voltage and power under load) is theoretically investigated. In the study, 4 different p-n pairs were formed for p-n pairs, forming thermoelectric modules, consisting of a combination of 4 different semiconductor materials of type Bi2Te3, Bi0.3Sb1.7Te3, PbSe0.5Te0.5 and Zn4Sb3. The thermoelectric generator using thermoelectric modules created from the determined p-n pairs was analyzed using the theoretical thermoelectric generator model developed in the Matlab/Simulink program in the previous study. In the theoretical model, the engine coolant temperature and flow values were used besides the temperature and flow rate of the exhaust gas obtained from experimental studies carried out in the 1500-4000 rpm range of a two-cylinder spark-ignition engine. The findings show that the thermoelectric generator produced the highest power output of the under the electrical load with the thermoelectric modules which is created using the Bi0.3Sb1.7Te3 and Bi2Te3 type semiconductors for the p-n pairs, respectively. Also, using the thermoelectric generator created by connecting twenty thermoelectric modules in series, 86.53 W (output current = 1.073 A and output voltage = 80.64 V) DC electrical power was obtained by the temperature difference of ΔT = 162.4 K at 4000 rpm engine speed.
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