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Validation of SCIAMACHY limb NO2 profiles using solar occultation measurements

机译:使用太阳掩星测量验证SCIAMACHY肢体NO2分布

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摘要

The increasing amounts of reactive nitrogen in the stratosphere necessitateaccurate global measurements of stratospheric nitrogen dioxide (NO). Overthe past decade, the SCIAMACHY (SCanning Imaging Absorption spectroMeter forAtmospheric CHartographY) instrument on ENVISAT (European EnvironmentalSatellite) has been providing global coverage of stratospheric NO every 6days. In this study, the vertical distributions of NO retrieved fromSCIAMACHY limb measurements of the scattered solar light are validated bycomparison with NO products from three different satellite instruments(SAGE II, HALOE and ACE-FTS). The retrieval algorithm based on the informationoperator approach is discussed, and the sensitivity of the SCIAMACHY NOlimb retrievals is investigated. The photochemical corrections needed to makethis validation feasible, and the chosen collocation criteria are described.For each instrument, a time period of two years is analyzed with severalhundreds of collocation pairs for each year. As NO is highly variable, thecomparisons are performed for five latitudinal bins and four seasons. In the 20to 40 km altitude range, mean relative differences between SCIAMACHY and otherinstruments are found to be typically within 20 to 30%. The mean partialNO columns in this altitude range agree typically within 15% (both globalmonthly and zonal annual means). Larger differences are seen for SAGE IIcomparisons, which is consistent with the results presented by other authors.For SAGE II and ACE-FTS, the observed differences can be partially attributedto the diurnal effect error.
机译:平流层中反应性氮的数量不断增加,因此需要对平流层二氧化氮(NO)进行准确的全局测量。在过去的十年中,ENVISAT(欧洲环境卫星)上的SCIAMACHY(大气压制图成像成像吸收光谱仪)仪器每6天提供一次全球平流层NO覆盖率。在这项研究中,通过比较来自三种不同卫星仪器(SAGE II,HALOE和ACE-FTS)的NO产物,验证了从SCIAMACHY肢体测量的散射太阳光中获得的NO的垂直分布。讨论了基于信息算子方法的检索算法,并研究了SCIAMACHY NOlimb检索的敏感性。为了使该验证可行,需要进行光化学校正,并描述所选的搭配标准。对于每种仪器,将分析两年的时间,每年分析数百个搭配对。由于NO的变化很大,因此对五个纬度箱和四个季节进行比较。在20至40公里的海拔范围内,SCIAMACHY与其他仪器之间的平均相对差异通常在20%至30%之内。在此高度范围内,partialNO列的平均数通常在15%以内(全球月度和区域年均值)。在SAGE II比较中观察到较大的差异,这与其他作者的结果一致。对于SAGE II和ACE-FTS,观察到的差异可以部分归因于昼夜效应误差。

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