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A novel method for deriving the aerosol hygroscopicity parameter based only on measurements from a humidified nephelometer system

机译:仅基于加湿浊度仪系统的测量值得出气溶胶吸湿性参数的新方法

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摘要

Aerosol hygroscopicity is crucial for understanding rolesof aerosol particles in atmospheric chemistry and aerosol climate effects.Light-scattering enhancement factor (RH, ) is one of theparameters describing aerosol hygroscopicity, which is defined as(RH, ) = (RH, )∕(dry, ), where(RH, ) or (dry, ) represents atwavelength under certain relative humidity (RH) or dry conditions.Traditionally, an overall hygroscopicity parameter can beretrieved from measured (RH, ), hereinafter referred to as, by combining concurrently measured particle numbersize distribution (PNSD) and mass concentration of black carbon. In thispaper, a new method is proposed to directly derive based only on measurements from a three-wavelength humidified nephelometersystem. The advantage of this newly proposed approach is that can be estimated without any additional informationabout PNSD and black carbon. This method is verified with measurements fromtwo different field campaigns. Values of estimatedfrom this new method agree very well with those retrieved by using thetraditional method: all points lie near the 1 : 1 line and the square ofcorrelation coefficient between them is 0.99. The verification resultsdemonstrate that this newly proposed method of deriving is applicable at different sites and in seasons ofthe North China Plain and might also be applicable in other regions aroundthe world.
机译:气溶胶吸湿性对于理解气溶胶颗粒在大气化学和气溶胶气候效应中的作用至关重要。光散射增强因子(RH,)是描述气溶胶吸湿性的参数之一,定义为(RH,)=(RH,)∕(干,(),其中(RH,)或(dry,)代表在一定相对湿度(RH)或干燥条件下的波长。传统上,可以从测得的(RH,)中检索出总体吸湿性参数,以下简称为黑碳的粒径分布(PNSD)和质量浓度。在本文中,提出了一种仅基于三波长加湿浊度仪系统的测量结果直接推导的新方法。这种新提出的方法的优点是无需任何有关PNSD和黑碳的任何附加信息即可进行估算。通过两个不同的野战活动的测量结果验证了该方法。这种新方法的估计值与使用传统方法获得的值非常吻合:所有点都位于1:1线附近,它们之间的相关系数的平方为0.99。验证结果表明,这种新提出的推导方法适用于华北平原的不同地点和季节,也可能适用于世界其他地区。

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