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Modification of Alumina Inclusions in SWRS82B Steel by Adding Rare Earth Cerium

机译:通过加入稀土铈改造SWRS82B钢中的氧化铝夹杂物

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摘要

The aluminum oxide inclusions in SWRS82B steel seriously affect the drawing performance of the steel strand. In this study, the influence of different additions of cerium (within the range of 0–0.034%) on the composition, morphology, size, number, and distribution of alumina inclusions was studied by scanning electron microscope and energy spectrum analyzer. The evolution of the composition of inclusions with different cerium additions was calculated based on classical thermodynamics and Factsage software calculation. The thermodynamic calculated results were consistent with the experimental results. It indicates that the modification route of Al2O3 inclusions in SWRS82B steel by increased cerium additions is as follows: Al2O3 → Ce2S3 + CeAlO3 + Ce2O2S + Al2O3 → Ce2S3 + CeAlO3 + Ce2O2S/Ce2S3 + Ce2O2S → Ce2S3 + Ce2O2S. Besides, when the amount of cerium is in the range of 0.023% to 0.030%, CeAlO3 inclusions gradually disappear. The best characteristics of inclusions in this study were obtained in experimental samples with cerium addition of 0.023%, in which the minimum size of inclusions is in the range of 3.52–4.84 μm and mostly uniform distribution. Finally, the mechanism on the modification by cerium was discussed based on the composition evolution of inclusion during solidification with Factsage calculation and experimental results. The compositions of inclusions were also analyzed based on the inclusion evolution model.
机译:SWRS82B钢中的氧化铝夹杂物严重影响钢绞线的拉伸性能。在该研究中,通过扫描电子显微镜和能谱分析仪研究了氧化铝夹杂物的组成,形态,大小,数和0-0.034%范围内)的不同添加的影响,氧化铝夹杂物的分布。基于经典热力学和事实软件计算,计算了不同铈添加剂的夹杂物组合物的演变。热力学计算结果与实验结果一致。它表明,通过增加的铈添加剂的SWRS82B钢中的Al2O3夹杂物的修饰路线如下:Al2O3→Ce2S3 + CealO3 + Ce2O2s + Al2O3→Ce2S3 + CealO3 + Ce2O2S / Ce2S3 + Ce2O2S→Ce2S3 + Ce2O2S。此外,当铈的量在0.023%至0.030%的范围内时,CealO3夹杂物逐渐消失。在该研究中的最佳夹杂物特征是在实验样品中获得的,其中铈添加为0.023%,其中夹杂物的最小尺寸范围为3.52-4.84μm,并且分布大多均匀。最后,基于凝固过程中夹杂物的凝固过程中的成分演化进行了铈的改性机制,具有事实计算和实验结果。还基于包含进化模型分析夹杂物的组合物。

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