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Templated self-assembly of Si-containing block copolymers for nanoscale device fabrication

机译:用于纳米级器件制造的含Si嵌段共聚物的模板化自组装

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摘要

Block copolymers have been proposed for self-assembled nanolithography because they can spontaneously form well-ordered nanoscale periodic patterns of lines or dots in a rapid, low-cost process. By templating the selfassembly, patterns of increasing complexity can be generated, for example arrays of lines with bends or junctions. This offers the possibility of using a sparse template, written by electron-beam lithography or other means, to organize a dense array of nanoscale features. Pattern transfer is simplified if one block is etch resistant and one easily removable, and in this work we use a diblock copolymer or a triblock terpolymer with one Sicontaining block such as polydimethylsiloxane or polyferrocenylsilane, and one or two organic blocks such as polystyrene or polyisoprene. Removal of the organic block(s) with an oxygen plasma leaves a pattern of Sicontaining material which can be used as an etch mask for subsequent pattern transfer to make metallization lines or magnetic nanostructures with feature sizes below 10 nm and periodicity below 20 nm.
机译:已经提出了用于自组装的纳米线的嵌段共聚物,因为它们可以在快速,低成本的过程中自发地形成有序有序的纳米级周期性图案或点。通过对自体叠加,可以产生增加复杂性的模式,例如具有弯曲或结的线阵列。这提供了使用稀疏模板,由电子束光刻或其他方式写入的可能性,以组织密集的纳米级功能。如果一个块是耐蚀刻的,并且在该工作中,则简化图案转移,并且在该工作中,我们使用二嵌段共聚物或三嵌段三元共聚物,其中一个色甲烷块如聚二甲基硅氧烷或聚二苯基硅烷,以及一种或两个有机嵌段,如聚苯乙烯或聚异戊二烯。用氧等离子体去除有机嵌段留下了种植体的图案,其可以用作蚀刻掩模,用于后续图案转移,以使金属化线或磁性纳米结构具有低于10nm的特征尺寸和低于20nm的周期性。

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