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Ruthenium-Catalyzed Oxygenative Transformation of Terminal Propargyl Alcohols to Metheyleneketenes via Allenylidene Intermedia-tes: Synthesis ofα,β-Unsaturated Carboxylic Acid Derivatives

机译：通过联烯基内酯-TES-α，β-不饱和羧酸衍生物的合成，钌催化末端炔丙醇的末端炔丙醇的可透化转化为甲基炔丙醇：α，β-不饱和羧酸衍生物

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Xinyu Wang; Qihuan Li; Tingbin Wen;
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年度 2021
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1. Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched‐chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched‐ and straight‐chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight‐ and branched‐chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) [J] . EFSA Journal . 2010,第11期

机译：香精基团评估报告62 Rev1（FGE.62 Rev1）：考虑了由JECFA评估的直链和支链脂族不饱和，未共轭的醇，醛，酸和相关酯（61 st 和68
2. Ruthenium-catalyzed addition of carboxylic acids or cyclic 1,3-dicarbonyl compounds to propargyl alcohols [J] . Stefanie Berger, Edgar Haak Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第50期

机译：钌催化的羧酸或环状1,3-二羰基化合物向炔丙醇的加成
3. Scientific Opinion on Flavouring Group Evaluation 10, Revision 3 (FGE.10Rev3): Aliphatic primary and secondary saturated and unsaturated alcohols, aldehydes, acetals, carboxylic acids and esters containing an additional oxygenated functional group and lactones from chemical groups 9, 13 and 30 [J] . EFSA Journal . 2012,第3期

机译：关于调味剂基团评估10的科学意见，修订版3（FGE.10Rev3）：脂肪族的伯和仲饱和和不饱和醇，醛，缩醛，羧酸和含有额外氧化官能团的酯以及化学组9、13和30的内酯
4. Highly Efficient Synthesis of Allenyltitanium Reagents Propargyl Alcohol Derivatives.Practical Synthesis of Homopargyl Alcohols [C] . Fang-Long Yang International symposium for Chinese organic chemists . 2000

机译：高效合成亚甲硝基试剂炔丙醇衍生物。常卤醇的实际合成
5. Molybdenum and palladium catalyzed asymmetric allylic alkylation of prochiral nucleophiles: Enantioselective synthesis of nonnatural alpha-amino acids and of tertiary alpha-hydroxy carboxylic acid derivatives. [D] . Franzini, Maurizio. 2005

机译：钼和钯催化的前手性亲核试剂的不对称烯丙基烷基化：非天然α-氨基酸和叔α-羟基羧酸衍生物的对映选择性合成。
6. Scientific Opinion on Flavouring Group Evaluation 5 Revision 3 (FGE.05Rev3): Branched‐ and straight‐chain unsaturated aldehydes dienals unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1 2 3 5 and 15 [O] . EFSA Food Additives and Flavourings (FAF), Maged Younes, Gabriele Aquilina, 2019

机译：关于调味剂基团评估5的科学意见修订版3（FGE.05Rev3）：支链和直链不饱和醛二烯不饱和和饱和羧酸及相关酯与饱和和不饱和脂族醇以及化学基团与苯乙酸有关的酯1、2、3、5和15
7. EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF); Scientific Opinion on Flavouring Group Evaluation 10, Revision 3 (FGE.10Rev3): Aliphatic primary and secondary saturated and unsaturated alcohols, aldehydes, acetals, carboxylic acids and esters containing an additional oxygenated functional group and lactones from chemical groups 9, 13 and 30 [O] . Larsen John Christian, Nørby Karin Kristiane, Beltoft Vibe Meister, 2012

机译：EFsa食品接触材料，酶，调味剂和加工助剂专家组（CEF）;关于调味组评价的科学观点10，修订版3（FGE.10Rev3）：脂肪族伯和仲饱和和不饱和醇，醛，缩醛，羧酸和含有额外氧化官能团的酯和来自化学基团9,13和30的内酯

Ruthenium-Catalyzed Oxygenative Transformation of Terminal Propargyl Alcohols to Metheyleneketenes via Allenylidene Intermedia-tes: Synthesis ofα,β-Unsaturated Carboxylic Acid Derivatives

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