A redetermination of the crystal structure of the mannitol complex NH4Mo2O5(C6H11O6)·H2O: hydrogen-bonding scheme and Hirshfeld surface analysis

摘要

The redetermined structure [for the previous study, see: Godfrey & Waters (1975). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-trihydroxyhexane-2,3,4-tris(olato)]bis[dioxidomolybdenum(V)] monohydrate, NH4[Mo2(C6H11O6)O5]·H2O, was obtained from an attempt to prepare a glutamic acid complex from the [Co2Mo10H4O38]6− anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H...O, O—H...O and C—H...O hydrogen bonds. A Hirshfeld surface analysis was also performed.