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Synthesis of Pure Micro- and Nanopyrite and Their Application for As (III) Removal from Aqueous Solution

机译:纯微烷和纳米吡啶的合成及其施用作为(III)从水溶液中除去

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摘要

Arsenic is one of the materials that has a worldwide concern because of its high toxicity and chronic effects on human health. The existence of arsenic as As (III) is about 56 times poisonous as As (V) and more difficult to process. The investigation takes the pyrite as an adsorbent to remove As (III) from waste water. Different morphology and granularity of pyrite were synthesized by hydrothermal and liquid-phase precipitation methods, respectively. The findings show that the addition of pyrite nanoparticles to the solution provided highest As (III) removal efficiency of 88.53%. 1 gL−1 pyrite nanoparticles can reduce the concentration of arsenite in the waste water from an initial As content of 30 mgL−1 to 3.4 mgL−1 at pH 11. Under the similar operating conditions, the synthetic micropyrite and natural pyrite have a lower As (III) removal; both were less than 70%. In addition, the synthetic pyrite nanowires obtained 86.70% removal efficiency of arsenite. The results confirmed that the morphology and granularity of pyrite can significantly influence the adsorption of arsenite removal from aqueous solution.
机译:由于其对人体健康的高毒性和慢性效应,砷是全球关注的材料之一。砷的存在是(III)的存在约56次,如(v),更难以处理。该研究将黄铁矿作为吸附剂,以从废水中除去(III)。通过水热和液相沉淀方法合成了硫铁矿的不同形态和粒度。结果表明,将硫铁矿纳米颗粒添加到溶液中提供的最高(III)除去效率为88.53%。 1GL-1硫铁矿纳米颗粒可以从初始作为pH11的含量降低废水中的砷酸盐浓度。在pH11中的含量为30mg-1至3.4mg1。在类似的操作条件下,合成的微吡化物和天然黄铁矿具有较低的作为(iii)删除;两者都小于70%。此外,合成硫铁矿纳米线获得86.70%的砷酸盐效率。结果证实,黄铁矿的形态和粒度可以显着影响来自水溶液的砷酸盐的吸附。

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