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Investigation of the dynamical slowing down process in soft glassy colloidal suspensions: comparisons with supercooled liquids

机译:软玻璃胶体悬浮液动力减速过程的调查:超冷液体比较

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摘要

The primary and secondary relaxation timescales of aging colloidalsuspensions of Laponite are estimated from intensity autocorrelation functionsobtained in dynamic light scattering (DLS) experiments. The dynamical slowingdown of these relaxation processes are compared with observations in fragilesupercooled liquids by establishing a one-to-one mapping between the waitingtime since filtration of a Laponite suspension and the inverse of thetemperature of a supercooled liquid that is rapidly quenched towards its glasstransition temperature. New timescales, such as the Vogel time and the Kauzmanntime, are extracted to describe the phenomenon of dynamical arrest in Laponitesuspensions. In results that are strongly reminiscent of those extracted fromsupercooled liquids approaching their glass transitions, it is demonstratedthat the Vogel time calculated for each Laponite concentration is approximatelyequal to the Kauzmann time, and that a strong coupling exists between theprimary and secondary relaxation processes of aging Laponite suspensions.Furthermore, the experimental data presented here clearly demonstrates theself-similar nature of the aging dynamics of Laponite suspensions within arange of sample concentrations.
机译:从动态光散射(DLS)实验中获得的强度自相关函数估算Laponite老化胶体悬浮液的主要和次要松弛时间尺度。通过建立从Laponite悬浮液过滤以来的等待时间与迅速冷却至其玻璃化转变温度的过冷液体温度的倒数之间的一对一映射关系,将这些弛豫过程的动态减慢与易碎过冷液体中的观察结果进行了比较。提取了新的时标,例如Vogel时间和Kauzmanntime,以描述Laponitessuspensions中的动态停滞现象。结果非常令人联想到从过冷液体中接近其玻璃化转变的过程中提取的结果,结果表明,针对每种Laponite浓度计算的Vogel时间近似等于Kauzmann时间,并且老化Laponite悬浮液的初次和二次弛豫过程之间存在强耦合此外,此处提供的实验数据清楚地证明了Laponite悬浮液在一系列样品浓度下的老化动力学具有相似性。

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