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A new approach to crystal growth of Hg1−xCdxTe by the travelling heater method (THM)

机译:用行进加热法(THm)研究Hg1-xCdxTe晶体生长的新方法

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摘要

Crystal growth by the travelling heater method (THM) is reported using a source material preparation process that is different from all methods used before. Non-stoichiometric (Hg, Cd)Te melts were homogenized and quenched to prevent macroscopic segregation effects. Inclusions of excess Te were removed during a first THM pass, resulting in stoichiometric solid alloys with a shift of the mole fraction towards higher CdTe contents. The amount of the shift, dependent on the Te excess and on the equilibrium temperature of the first THM run, was calculated and taken into account in the preparation of x=0.22 and x=0.30 Hg1-xCdxTe single crystals. Source material ingots, as well as THM single crystals, were characterized with special emphasis of the compositional homogeneity. Radial as well as axial homogeneity are comparable with the best results on THM crystals reported so far. The described method can be used in growing all materials for which THM is possible. However, quantitative calculation requires the exact knowledge of the particular ternary phase diagram.
机译:通过行进加热器方法(THM)进行的晶体生长是使用​​与之前使用的所有方法不同的原材料制备过程来报告的。将非化学计量的(Hg,Cd)Te熔体均质化并淬火,以防止宏观偏析作用。在第一次THM扫描过程中,多余的Te夹杂物被去除,导致化学计量的固态合金的摩尔分数向更高的CdTe含量偏移。计算出的偏移量取决于Te的过量和首次THM运行的平衡温度,并在制备x = 0.22和x = 0.30 Hg1-xCdxTe单晶时加以考虑。原料锭以及THM单晶的特征是特别强调成分均匀性。径向和轴向均匀性与迄今为止报道的THM晶体的最佳结果相当。所描述的方法可用于生长可能使用THM的所有材料。但是,定量计算需要特定三元相图的确切知识。

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