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Analytical study of the XIV century wall painting and lime mortars in the 'St. George' church in Staro Nagoričane, Republic of Macedonia

机译:马其顿共和国staroNagoričane“圣乔治”教堂的十四世纪壁画和石灰砂浆的分析研究

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摘要

This work presents the first comprehensive study of the wall painting in the “St. George” church accomplished mainly by means of Fourier Transform Infrared Spectroscopy using Diffuse Reflectance and Micro-Infrared method (FTIR/DRS/Micro-IR) and the other analytical techniques Optical microscopy (OM), X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD) and Inductively Coupled Plasma – Mass Spectrometry (ICP-MS). The main research objective was characterization of the artistic palette and painting technique, but also determination of the degradation products and observed alterations to the wall painting. Additionally, the lime mortars (plaster and renders) located immediately behind the studied wall painting were analyzed. The analysis demonstrated that mainly natural/mineral pigments were used in the artwork and the majority of painting was executed in combination of fresco and lime-painting technique. The major risk factor in the painting deterioration was found to be the salt efflorescence, which mostly occurred as oxalates and sulfates. ud udKeywords: wall painting; pigments; binders; degradation products; lime mortars
机译:这项工作是对“圣约翰大教堂”中壁画的首次全面研究。乔治教堂主要通过傅里叶变换红外光谱技术(使用漫反射和微红外方法(FTIR / DRS / Micro-IR))以及其他分析技术来完成,例如光学显微镜(OM),X射线荧光(XRF),X-射线衍射(XRD)和电感耦合等离子体质谱(ICP-MS)。主要研究目的是表征艺术调色板和绘画技术,还确定降解产物和观察到的壁画变化。此外,还分析了紧挨着研究的壁画后面的石灰砂浆(灰泥和抹灰)。分析表明,艺术品中主要使用天然/矿物颜料,大部分绘画是结合壁画和石灰绘画技术执行的。发现油漆变质的主要危险因素是盐的泛黄,其主要以草酸盐和硫酸盐的形式发生。 ud ud关键字:壁画;颜料粘合剂降解产物;石灰砂浆

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