首页> 外文OA文献 >HETEROGENA FOTOKATALITSKA OKSIDACIJA ZA ODSTRANITEV BISFENOLA A IZ VODE NA OSNOVI RAZLIČNIH TiO2/GRAFENOV OKSID (GO) NANOKOMPOZITOV
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HETEROGENA FOTOKATALITSKA OKSIDACIJA ZA ODSTRANITEV BISFENOLA A IZ VODE NA OSNOVI RAZLIČNIH TiO2/GRAFENOV OKSID (GO) NANOKOMPOZITOV

机译:TiO2 /氧化石墨烯(GO)纳米复合材料的异相光催化氧化去除水中的双酚A

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摘要

Since water is an essential substance for all life on earth, it is therefore vital to prevent its pollution and to improve wastewater purification processes. There is a vast number of pollutants which can contaminate water, of which bisphenol A (known as an endocrine disruptor) is the pollutant studied herein. In this study, several TiO2/GO based nanocomposites with various GO loadings (2, 4, 10, 20 and 40%) and differently shaped nanocrystalline TiO2 phases (titanate nanotubes (TNTs) and calcined titanate nanotubes (TNTs_500)) were synthesised. All of the nanocomposites were characterised through SEM, UV-vis-DR, TGA, BET, FT-IR and CHNS analyses and were used in the heterogeneous photocatalytic degradation of bisphenol A and compared to the activity of pure TNTs and TNT_500 photocatalysts. All TiO2/GO nanocomposites exhibit much better activity than pure TNTs and TNTs_500 catalysts. The conversion of the BPA was analysed using HPLC and the mineralisation was analysed using a TOC analysis. The best experiment was performed with TNTs_500 + 10% GO composite, which can be attributed to the TiO2 crystalline structure obtained. According to the results obtained, TiO2 + 10% GO was found to exhibit the best degradation ratio, which can be ascribed to the fact that excessive GO can act as a charge carrier recombination centre and promotes the recombination of electron-hole pairs in reduced GO.
机译:由于水是地球上所有生命必不可少的物质,因此防止水污染和改善废水净化工艺至关重要。有大量的污染物可以污染水,其中双酚A(称为内分泌干扰物)是本文研究的污染物。在这项研究中,合成了几种具有各种GO负载(2%,4%,10%,20%和40%)和不同形状的纳米TiO2相(钛纳米管(TNTs)和煅烧钛酸酯纳米管(TNTs_500))的TiO2 / GO基纳米复合材料。通过SEM,UV-vis-DR,TGA,BET,FT-IR和CHNS分析对所有纳米复合材料进行表征,并将其用于双酚A的非均相光催化降解,并与纯TNT和TNT_500光催化剂的活性进行比较。所有的TiO2 / GO纳米复合材料均比纯TNT和TNTs_500催化剂表现出更好的活性。使用HPLC分析BPA的转化率,并使用TOC分析分析矿化作用。最好的实验是使用TNTs_500 + 10%GO复合材料进行的,这可以归因于所获得的TiO2晶体结构。根据得到的结果,发现TiO 2 + 10%GO表现出最佳的降解率,这可以归因于过量的GO可以充当电荷载流子的复合中心并促进还原的GO中电子-空穴对的复合。 。

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    Veternik Ana;

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  • 年度 2017
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