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The effect of zinc stearate on thermal degradation of paraffin wax

机译:硬脂酸锌对石蜡热降解的影响

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摘要

In this research, the effects of zinc stearate addition on paraffin wax degradation were investigated by differential scanning calorimetry (DSC) and thermogravimetry (TG). The apparent activation energies of wax decomposition in nitrogen and air atmospheres were determined as 76 and 37 kJ mol-1, respectively applying Kissinger method to TG data. The degradation rate constants of paraffin containing zinc stearate (0.1-0.5%) were found to be almost two times greater than that of paraffin only in air atmosphere. However, zinc stearate did not affect the rate constants in nitrogen significantly.
机译:在这项研究中,通过差示扫描量热法(DSC)和热重法(TG)研究了硬脂酸锌添加对石蜡降解的影响。分别将基辛格方法应用于TG数据,确定在氮气和空气中蜡分解的表观活化能分别为76和37 kJ mol-1。发现仅在空气中,含硬脂酸锌的石蜡的降解速率常数(0.1-0.5%)几乎比石蜡的降解速率常数大两倍。但是,硬脂酸锌并未显着影响氮中的速率常数。

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