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美国政府科技报告
>RESEARCH AND DEVELOPMENT ON THE THERMODYNAMICS OF SIMPLE GASESnADSORBED ON SOLIDS THEORY OF HEATS OF ADSORPTION ON A UNIFORM SURFACE EFFECT OF LATERAL INTERACTION AND GRAIN BOUNDARIES 30 April 1956 to 10 October 1956
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RESEARCH AND DEVELOPMENT ON THE THERMODYNAMICS OF SIMPLE GASESnADSORBED ON SOLIDS THEORY OF HEATS OF ADSORPTION ON A UNIFORM SURFACE EFFECT OF LATERAL INTERACTION AND GRAIN BOUNDARIES 30 April 1956 to 10 October 1956
The use of a model whereby the adsorbent surface is composed of edge sites and flat sites, the former being twice the energy of the latter, shows that the effect of edge sites on the surface is too small to be seen with any great precision. The graphitized carbon black surface, therefore, appears to be essentially uniform for adsorption. The observed lateral interaction energies of neon, argon, and krypton on graphite indicate patch-wise adsorption with each patch under compression,
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