TRANSITION PROBABILITTIES OF MOLECULAR BAND SYSTEMSnXV. The Influence of the Vibration-Rotation Interaction on The Intensities Of Diatomic Molecular Electronic Lines and Bands

摘要

The effect of the vibration-rotation interaction on the theoretical intensities of diatomic electronic bands is calculated on the basis of the Morse-Pekeris oscillator. The results for bands of 3 systems show that the effect is usually quite small, often negligible, but there are cases and circumstances (e.g. high temperature work) where the effect may have to be taken into account.