SOLUTIONS FOR COMPLEX SYSTEMS OF CHEMICAL REACTION KINETICS PartⅠ. An Irreversible Unimolecular Reaction Followed By a Second Irreversible Unimolecular Reaction. Supplement Ⅰ.

摘要

In a previous report (WADC TN 59-243, Part I), the analyticalnsolutions of the rate equations for the system were explored for characteristic features which are useful to the kineticist in determining the rate constants from fragmentary experiment data. The present rate amplifies and generalizes the earlier findings by introducing a reduced time which facilitates the problems of curve fitting. In addition, certain simplifying approximations are discussed and the limits of their validity are defined.